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Prussian blue

physical science Maturity 5-7 Next article →

Prussian blue is a very dark blue pigment. It is a special kind of substance called a synthetic pigment. This means people made it in a lab rather than finding it in nature. It is also known by many other names like Berlin blue or Paris blue.

Берлинская лазурь
Берлинская лазурь

This color is very important because it is stable. It stays bright and does not fade easily in the light. Many different people use it for art, science, and even medicine.

Making this blue involves a step-by-step change called oxidation. It starts with white solids known as ferrous ferrocyanide salts. When these salts undergo oxidation, they turn into a deep blue color. This happens because the iron in the material changes its state. The final result is a very fine powder called a colloidal dispersion.

This means the tiny particles stay floating in a liquid even though they do not dissolve in water. The exact shade of blue can change based on how big these tiny particles are.

This color was discovered by accident in the early 1700s. A paint maker named Johann Jacob Diesbach likely made it in Berlin around 1706. He was actually trying to make a red dye using cochineal. He used potash that had been tainted with blood. Instead of red, the mixture reacted to create iron ferrocyanide.

Great Wave off Kanagawa2
Great Wave off Kanagawa2

This mistake led to the first modern synthetic pigment. By 1708, a man named Johann Leonhard Frisch began selling it across Europe.

Prussian blue has been used in many famous ways throughout history. It was used in the 19th-century Japanese woodblock prints by artists like Hokusai.

Great Wave off Kanagawa2
Great Wave off Kanagawa2

In Germany, it was the main color for the coats worn by Prussian Army soldiers.

Königlich preussische Infanterie-Offiziere - Edmund Rabe
Königlich preussische Infanterie-Offiziere - Edmund Rabe

It is also the blue used to make technical blueprints. In medicine, it is a very important tool. It is on the World Health Organization's List of Essential Medicines. It can be used as an antidote for poisoning from metals like thallium or caesium.

Even though it is made from cyanide salts, the pigment is not toxic. This is because the cyanide groups are tightly bound to the iron. This keeps the dangerous parts from escaping into the body. The pigment works in medicine through a process called ion-exchange. This means it can swap tiny parts to grab onto certain metals.

Iron-coordination-in-simplified-Prussian-blue-from-xtal-xray-3D-bs-17
Iron-coordination-in-simplified-Prussian-blue-from-xtal-xray-3D-bs-17

This helps pull the poison out of a person. It is a great example of how a mistake in a lab can lead to a helpful discovery.

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🖼️ Images & Media (10)
File:Great Wave off Kanagawa2.jpg
Great Wave off Kanagawa2.jpg
File:Берлинская_лазурь.jpg
Берлинская_лазурь.jpg
File:Königlich preussische Infanterie-Offiziere - Edmund Rabe.png
Königlich preussische...
File:HexacyanidoferratIII 2.svg
HexacyanidoferratIII 2.svg
File:Iron-coordination-in-simplified-Prussian-blue-from-xtal-xray-3D-bs-17.png
Iron-coordination-in-simplified-Prussian-b...
File:Idealized, defect-free Prussian Blue.svg
Idealized, defect-free Prussian Blue.svg
File:Prussian Blue Powder XRD Profile, Simulated.jpg
Prussian Blue Powder XRD Profile, Simulated.jpg
File:Hydrated-Prussian-blue-unit-cell-a-centroids-all-OH-tilt-3D-bs-17.png
Hydrated-Prussian-blue-unit-cell-a-centroi...
File:The Great Clock following restoration - May 2022 (52120750076).png
The Great Clock following restoration -...
File:2016-Wu 2.png
2016-Wu 2.png
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