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Prussian blue

physical science Maturity 5-7 Next article →

Prussian blue is a deep, dark blue pigment used widely in art, industry, and medicine. It is chemically known as iron(III) hexacyanoferrate(II). This substance is significant because it was the first modern synthetic pigment. Before its discovery, artists relied on expensive or less stable blues. Examples include ultramarine, which is made from the semi-precious stone lapis lazuli. Other options included indigo dye, smalt, or Tyrian purple. Prussian blue offered a stable and lightfast alternative that did not fade easily.

Берлинская лазурь
Берлинская лазурь

The creation of this pigment relies on a process called oxidation. It begins with white solids known as ferrous ferrocyanide salts. These salts have the chemical formula Fe4[Fe(CN)6]3. When these salts undergo oxidation, they transform into the deep blue pigment. This can be achieved by using hydrogen peroxide or sodium chlorate. The oxidation changes the state of the iron within the material. This change in iron creates the intense color we see. The resulting pigment is a fine colloidal dispersion. This means the particles stay suspended in liquid without dissolving.

There are different forms and variations of this blue substance. One related substance is known as Turnbull's blue. For a long time, scientists thought it was different from Prussian blue. However, X-ray and electron diffraction show their structures are actually identical. The color differences only come from different impurities or particle sizes. Another variation is Prussian white, also called Berlin white. This is a totally reduced form where all the iron is Fe(II). It has a different molecular framework and a different color than the blue version.

Idealized, defect-free Prussian Blue
Idealized, defect-free Prussian Blue

The history of Prussian blue is a famous story of accidental discovery. Around 1706, a Berlin paint maker named Johann Jacob Diesbach was working with dyes. He was attempting to create a red lake pigment using cochineal. To do this, he needed potash, ferric sulfate, and dried cochineal. However, his potash was contaminated with blood. Instead of a red pigment, the mixture of blood, potash, and iron sulfate created iron ferrocyanide. This resulted in a distinct blue hue rather than the intended red.

Great Wave off Kanagawa2
Great Wave off Kanagawa2

Following its discovery, the pigment became a major commercial success. Johann Leonhard Frisch began promoting and selling it across Europe around 1708. The pigment was named "Prussian blue" by 1709. It quickly replaced the very expensive ultramarine in many applications. By 1710, painters at the Prussian court were already using it. It also reached Paris, where artists like Antoine Watteau used it. Even the Prussian Army used it for infantry and artillery uniforms.

Königlich preussische Infanterie-Offiziere - Edmund Rabe
Königlich preussische Infanterie-Offiziere - Edmund Rabe

Prussian blue has many important modern uses, especially in medicine. It is included on the World Health Organization's List of Essential Medicines. It acts as an antidote for heavy metal poisoning, such as thallium(I) or radioactive caesium. The pigment works through a process called ion-exchange. It has a high affinity for certain "soft" metal cations. This allows it to grab the poisonous metals and help remove them from the body. Interestingly, while it is made from cyanide salts, the pigment itself is not toxic. The cyanide groups are held very tightly by the iron atoms.

Iron-coordination-in-simplified-Prussian-blue-from-xtal-xray-3D-bs-17
Iron-coordination-in-simplified-Prussian-blue-from-xtal-xray-3D-bs-17

Beyond art and medicine, the substance has connections to energy science. Scientists are studying Prussian white as a possible material for batteries. Specifically, it is a candidate for cathode materials in sodium-ion batteries. The large framework of the crystal structure allows ions to move in and out easily. This movement happens during the charge and discharge cycles of the battery. This property could help create batteries with high energy densities. It also offers the possibility of high recharge rates even at low temperatures.

2016-Wu 2
2016-Wu 2
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🖼️ Images & Media (10)
File:Great Wave off Kanagawa2.jpg
Great Wave off Kanagawa2.jpg
File:Берлинская_лазурь.jpg
Берлинская_лазурь.jpg
File:Königlich preussische Infanterie-Offiziere - Edmund Rabe.png
Königlich preussische...
File:HexacyanidoferratIII 2.svg
HexacyanidoferratIII 2.svg
File:Iron-coordination-in-simplified-Prussian-blue-from-xtal-xray-3D-bs-17.png
Iron-coordination-in-simplified-Prussian-b...
File:Idealized, defect-free Prussian Blue.svg
Idealized, defect-free Prussian Blue.svg
File:Prussian Blue Powder XRD Profile, Simulated.jpg
Prussian Blue Powder XRD Profile, Simulated.jpg
File:Hydrated-Prussian-blue-unit-cell-a-centroids-all-OH-tilt-3D-bs-17.png
Hydrated-Prussian-blue-unit-cell-a-centroi...
File:The Great Clock following restoration - May 2022 (52120750076).png
The Great Clock following restoration -...
File:2016-Wu 2.png
2016-Wu 2.png
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