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Varnish

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Varnish is a clear, transparent, and hard protective coating used to shield surfaces. Unlike wood stain, which changes the color of the material, varnish is designed to be see-through. This allows the distinctive tones and natural grains of wood to remain visible.

Varnish
Varnish

While many varnishes have a natural yellowish shade due to their ingredients, they can also be pigmented with colors. They are available in many different sheens, ranging from high-gloss finishes to satin or flat appearances.

Oak flooring
Oak flooring

Because of its ability to create a durable film, varnish is a vital tool in woodworking and instrument making.

The creation of a varnish film involves a specific chemical process. Most traditional formulas consist of a resin, a drying oil, and a solvent. The solvent, such as alcohol or turpentine, thins the mixture so it can be applied easily with a brush. Once applied, the varnish must undergo a process called curing to become hard.

Polyurethane varnished table
Polyurethane varnished table

Resin varnishes harden quickly through the simple evaporation of the solvent. However, oil-based varnishes, like polyurethane or epoxy, undergo a more complex chemical reaction. These materials stay liquid or syrupy even after the solvent evaporates. They then transition through stages from tacky to gummy, and finally to a hard, dry state.

Different types of varnishes rely on different chemical mechanisms to harden. Drying oils, such as linseed, tung, or walnut oil, contain high levels of polyunsaturated fatty acids. These oils cure through an exothermic reaction, which is a process that produces heat, as the oil reacts with oxygen from the air. This process is known as autoxidation. In contrast, acrylic or waterborne varnishes dry primarily through the evaporation of water. The curing time for all varnishes can be influenced by environmental factors like heat and humidity. Exposure to energy sources, such as sunlight or ultraviolet light, can also speed up the drying and curing process.

History shows that humans have used varnishes for thousands of years. The word itself comes from the Mediaeval Latin *vernix*, meaning odorous resin. Ancient Egyptians were well known for using varnishing techniques. In East and South Asia, including India, China, and Japan, lacquer work was practiced at a very early date. During the Tang Dynasty in China, complex chemical formulas were used to produce varnish for silk clothes and bronze mirrors.

German, maple Violin
German, maple Violin

For centuries, many recipes for musical instruments were kept as guarded secrets because they were believed to improve the sound.

One unique type of varnish is shellac, which is a single-component resin varnish. Shellac is highly soluble in alcohol and has been used for centuries in the "French polish" finish for fine furniture. Interestingly, the source of shellac is an insect called *Kerria lacca*. This female lac insect lives in the forests of Thailand and Assam. She deposits a brittle, flaky secretion on tree bark to help her hold on to the trunk. This secretion is harvested and refined into the shellac used by woodworkers today.

Another specialized version is spar varnish, also known as marine or yacht varnish. This was originally developed to protect the wooden spars on ships. Spars are the wooden poles that hold up sails, and they must bend under the load of the wind. Because of this, spar varnish must be highly elastic. If a finish is too brittle, it will crack as the wood flexes, allowing water to seep underneath. While modern synthetic resins offer great UV resistance, spar varnish prioritizes staying flexible and adhering to moving wood.

Because of the chemicals involved, varnish requires strict safety precautions. Many varnishes are highly flammable in their liquid state. Furthermore, the curing process of drying oils is an exothermic reaction that generates heat. This heat can become intense enough that oil-soaked rags or paper can spontaneously combust. This means they can smolder and catch fire on their own, even several hours after they have been used. To prevent fires, manufacturers recommend disposing of used rags in water-filled containers.

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File:Varnish.jpg
Varnish.jpg
File:Oak flooring.jpg
Oak flooring.jpg
File:German, maple Violin.JPG
German, maple Violin.JPG
File:Polyurethane varnished table.jpg
Polyurethane varnished table.jpg
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