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Solid acid

physical science Maturity 9-11 Next article →

Solid acids are a very special kind of acid. Most acids we know dissolve in liquids. These acids do not dissolve in the liquid they work in. They are often used as heterogeneous catalysts. A catalyst is a tool that helps a chemical reaction happen.

Pile of benzoic acid crystals
Pile of benzoic acid crystals

These materials are often polymeric. This means they are made of long chains. They are usually stronger than simple solid acids like benzoic acid.

These acids work in many different ways. Some are inorganic solid acids. Examples include silico-aluminates like alumina or silico-aluminophosphate. Zeolites are a very common type of these materials.

Zeolite-ZSM-5-vdW
Zeolite-ZSM-5-vdW

You can also find sulfated zirconia in this group. Many transition metal oxides are also acidic. These include titania, zirconia, and niobia. Scientists use different ways to measure how strong these acids are.

Many industries use these acids to make things. One big job is called cracking. This happens in petroleum refining to make fuel.

Zeolite-ZSM-5-vdW
Zeolite-ZSM-5-vdW

Another big job is called alkylation. This is when benzene and ethylene join together. This process creates ethylbenzene. They are also used to make fine chemicals. They can even help make caprolactam. This happens by changing cyclohexanone oxime.

There are many specific names for these acids. Some are called Brønsted acids. One example is polystyrene sulfonate. Other examples include solid phosphoric acid and niobic acid. You might also see heteropolyoxometallates.

Zeolite-ZSM-5-vdW
Zeolite-ZSM-5-vdW

These acids help make alkylamines. They do this by using the amination of alcohols. This is a very important part of making chemicals. Each type of acid has a specific job to do.

You can find these acids in many places. They are used in large-scale factory processes. They are also used in smaller ways for acylations.

Zeolite-ZSM-5-vdW
Zeolite-ZSM-5-vdW

Some solid acids can even work in fuel cells. Fuel cells are used to create power. These acids help move things in the cell. They act as electrolytes to make the cell work. This shows how important they are to our world.

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File:Pile of benzoic acid crystals.jpg
Pile of benzoic acid crystals.jpg
File:Zeolite-ZSM-5-vdW.png
Zeolite-ZSM-5-vdW.png
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