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Plagioclase

earth science Maturity 7-9 Next article →

Plagioclase is a vital group of minerals within the feldspar family. It is the most abundant mineral group in the Earth's crust.

PlagioclaseFeldsparUSGOV
PlagioclaseFeldsparUSGOV

Because it is so common, geologists use it as a diagnostic tool. It helps them identify the origin and history of igneous rocks. This mineral is also found in the highlands of the Moon. Data from Mars suggests it may be the most abundant mineral on that planet's crust too.

Plagioclase is not one single mineral with one fixed recipe. Instead, it is a continuous solid solution series. This means the chemical makeup can change smoothly from one end to the other. The series ranges from albite to anorthite. Albite is a sodium feldspar with the formula NaAlSi3O8. Anorthite is a calcium feldspar with the formula CaAl2Si2O8.

Albite - Minas Gerais, Brazil
Albite - Minas Gerais, Brazil

These two endmembers can exist in any proportion.

This mixing happens because of how atoms fit into the crystal lattice. In this structure, sodium and calcium atoms can substitute for each other. While a calcium ion has a +2 charge and sodium has a +1 charge, they have nearly the same radius. To balance the different charges, a coupled substitution occurs. Aluminum (charge +3) replaces silicon (charge +4) in the tetrahedral sites. This allows the mineral to maintain its structure while changing its chemistry.

Scientists use specific names for different mixtures in the series. For example, anorthite contains 90 to 100 percent calcium. Bytownite contains 70 to 90 percent calcium.

Anorthite (Variety Bytownite)-464165
Anorthite (Variety Bytownite)-464165

Labradorite contains 50 to 70 percent calcium.

Labradorite Labrador MNHN Minéralogie
Labradorite Labrador MNHN Minéralogie

Andesine contains 30 to 50 percent calcium. Oligoclase contains 10 to 30 percent calcium.

01722 Andesine
01722 Andesine

Finally, albite contains only 0 to 10 percent calcium.

Oligoclase-4jg47b
Oligoclase-4jg47b

The history of studying these minerals is quite old. German mineralogist Johann Friedrich Christian Hessel showed the continuous series in 1826. Later, August Breithaupt introduced the name plagioclase in 1847. The name comes from Greek words for "oblique fracture." This refers to the mineral's unique cleavage angles. These planes meet at an angle of 93 to 94 degrees.

PlagioclaseFeldsparUSGOV
PlagioclaseFeldsparUSGOV

This specific angle helps geologists tell plagioclase apart from other feldspars.

Plagioclase forms through a process called Bowen's continuous reaction series.

Bowen's Reaction Series
Bowen's Reaction Series

As magma cools, different minerals crystallize at different temperatures. Anorthite has a much higher melting point than albite. Therefore, calcium-rich plagioclase is usually the first to crystallize from the melt. As the temperature drops, the remaining liquid becomes more sodium-rich. This causes the new crystals to become more sodium-rich over time. This process often creates compositional zoning. A single crystal might have a calcium-rich core and a sodium-rich rim.

Physical properties also change smoothly as the chemistry shifts. The specific gravity increases from 2.62 for albite to 2.76 for anorthite. The index of refraction also moves from 1.53 to 1.58. Most plagioclase is white or greyish-white. However, some varieties show amazing optical effects. Labradorite is famous for labradorescence. This is an iridescent display of colors caused by light refracting within the crystal.

labradorite detail
labradorite detail

This makes the mineral a fascinating subject for both scientists and collectors.

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🖼️ Images & Media (11)
File:PlagioclaseFeldsparUSGOV.jpg
PlagioclaseFeldsparUSGOV.jpg
File:LvMS-Lvm.jpg
LvMS-Lvm.jpg
File:Anorthite-rare08-38b.jpg
Anorthite-rare08-38b.jpg
File:Anorthite (Variety Bytownite)-464165.jpg
Anorthite (Variety Bytownite)-464165.jpg
File:Labradorite Labrador MNHN Minéralogie.jpg
Labradorite Labrador MNHN Minéralogie.jpg
File:01722 Andesine.jpg
01722 Andesine.jpg
File:Oligoclase-4jg47b.jpg
Oligoclase-4jg47b.jpg
File:Albite - Minas Gerais, Brazil.jpg
Albite - Minas Gerais, Brazil.jpg
File:labradorite detail.jpg
labradorite detail.jpg
File:Bowen's Reaction Series.png
Bowen's Reaction Series.png
File:Qapf diagram plutonic 05.svg
Qapf diagram plutonic 05.svg
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