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Pyroxene

earth science Maturity 11-13 Next article →

Pyroxene is a vital group of rock-forming inosilicate minerals. These minerals are essential components of many igneous and metamorphic rocks. They are also major parts of Earth's upper mantle. This deep layer of our planet consists mainly of olivine and pyroxene.

Peridot in basalt
Peridot in basalt

Because they are so common, they help geologists understand how rocks form. The group is highly diverse due to its chemical flexibility.

The internal structure of pyroxene is a single-chain silicate. It consists of parallel chains made of silica tetrahedra. A silica tetrahedron is a shape where one silicon ion is surrounded by four oxygen ions. In these chains, each silicon ion shares two oxygen ions with its neighbors. This creates long, continuous strands. These chains all face the same direction. On one side, they have two oxygen ions per tetrahedron. On the other side, they have only one. These single oxygen ions are called apical oxygen ions.

Microscopic image Pyroxene
Microscopic image Pyroxene

Pairs of these chains bond together at their apical sides using Y cations. Each Y cation is surrounded by six oxygen ions. This creates a structure that looks like interlocking I-beams. Additional X cations bond the outer faces of these I-beams to each other. This X-cation bonding provides charge balance but is relatively weak. This weakness results in the characteristic cleavage of the mineral.

Pyroxenes are classified into two main structural groups. The first group is the clinopyroxenes, which crystallize in the monoclinic system. The second group is the orthopyroxenes, which crystallize in the orthorhombic system.

Diopside-172005
Diopside-172005

The specific crystal system depends on how the ions are arranged. For example, the enstatite-ferrosilite series contains the mineral hypersthene. Hypersthene can exist in three different forms, called polymorphs. These include orthoenstatite and protoenstatite in the orthorhombic system. They can also form clinoenstatite in the monoclinic system. Increasing calcium levels can prevent the formation of orthorhombic phases. This shows how chemistry dictates the physical shape of the crystal.

The name pyroxene comes from Ancient Greek words meaning "fire stranger." This name reflects an early misunderstanding of the mineral. People found pyroxene crystals embedded in volcanic glass. They assumed the crystals were strange impurities inside the glass. We now know these minerals are simply early-forming. They crystallize from magma before the lava even erupts.

Orthopyroxenite (ALH84001)
Orthopyroxenite (ALH84001)

This discovery helps us track the cooling history of volcanic rocks.

Pyroxene chemistry is incredibly complex because the structure can hold many different cations. The general formula is XY(Si,Al)2O6. The X site can hold large ions like calcium, sodium, iron, or magnesium. It can also host zinc, manganese, or lithium. The Y site holds smaller ions like chromium, aluminum, magnesium, or titanium.

Microscopic image Pyroxene
Microscopic image Pyroxene

Because so many elements can substitute for one another, many different minerals exist. The International Mineralogical Association recognizes twenty specific pyroxene names. They have discarded 105 older names to keep the science organized. For instance, the pyroxene quadrilateral helps define common calcium-iron-magnesium minerals. The pyroxene triangle is used to name sodium-rich varieties.

Chemical substitutions allow pyroxenes to maintain charge neutrality. When a sodium ion with a 1+ charge enters the X site, the mineral needs more positive charge elsewhere. This often happens through a coupled substitution. For example, in jadeite, sodium is paired with aluminum in the Y site. Another method is the Tschermak substitution. This occurs when a 3+ ion occupies both a Y site and a T site. These complex chemical dances allow pyroxenes to exist in many different environments. This flexibility makes them a primary subject in mineralogical studies.

Pyroxenes are not just found on Earth. They are important for studying the history of our solar system. The Curiosity rover used X-ray diffraction to analyze Martian soil.

PIA16217-MarsCuriosityRover-1stXRayView-20121017
PIA16217-MarsCuriosityRover-1stXRayView-20121017

This analysis revealed the presence of pyroxene, olivine, and feldspar on Mars. Finding these minerals helps scientists understand the geological processes of other planets. By studying pyroxene, we gain a clearer picture of how rocky worlds evolve over billions of years.

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File:Diopside-172005.jpg
Diopside-172005.jpg
File:PIA16217-MarsCuriosityRover-1stXRayView-20121017.jpg
PIA16217-MarsCuriosityRover-1stXRayView-20...
File:Microscopic image Pyroxene.jpg
Microscopic image Pyroxene.jpg
File:Peridot in basalt.jpg
Peridot in basalt.jpg
File:Orthopyroxenite (ALH84001).gif
Orthopyroxenite (ALH84001).gif
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