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Chlorite group

earth science Maturity 7-9 Next article →

The chlorite group consists of phyllosilicate minerals that are very common in the Earth's crust.

Quartz-Chlorite-Group-139575
Quartz-Chlorite-Group-139575

These minerals are often found in low-grade metamorphic rocks and altered igneous rocks. Their name comes from the Greek word "chloros," which means green. This name refers to the distinct green color they often provide to rocks. It is important to note that chlorite minerals do not contain the element chlorine. Instead, they are defined by their specific crystal structures and chemical compositions. They play a vital role in helping geologists understand the history of rocks.

To understand how chlorite works, we must look at its TOT-O structure. This structure is made of alternating layers. A TOT layer is a sandwich of three parts: a tetrahedral layer, an octahedral layer, and another tetrahedral layer. In minerals like talc, these layers are electrically neutral and held together by weak van der Waals forces. However, chlorite is different because it contains aluminum instead of silicon in its structure. This substitution gives the TOT layers an overall negative charge. To balance this, the layers are bound together by positively charged O layers, which are sometimes called brucite layers.

Chlorite schist
Chlorite schist

This arrangement makes chlorite a nonswelling clay mineral. Unlike some clays, it does not adsorb water into the spaces between its layers.

Chlorite minerals exhibit a wide variety of chemical compositions. This variety happens because magnesium, iron, aluminum, and silicon can substitute for one another within the crystal structure. There is a complete solid solution series between the two most common end members. These are magnesium-rich clinochlore and iron-rich chamosite. Other species in the group can include manganese, zinc, lithium, and calcium. Because the chemistry changes so much, the physical, optical, and X-ray properties of the minerals vary as well. This chemical flexibility allows chlorite to exist under many different temperature and pressure conditions.

Geologists use chlorite to identify specific environments in the Earth. In the Scottish Highlands, G.M. Barrow conducted pioneering work on metamorphic facies. He identified the chlorite zone as the area of the mildest metamorphism. In modern petrology, chlorite is the diagnostic mineral for the greenschist facies. This facies is characterized by temperatures and pressures near 5 kbar. If temperatures rise significantly higher, chlorite is destroyed by chemical reactions. It may react with potassium feldspar or phengite mica to produce biotite, muscovite, and quartz. At even higher temperatures, the mineral may be destroyed while releasing water vapor.

These minerals appear in many different geological settings. They are common in metamorphic rocks formed from mafic or pelitic rocks. In igneous rocks, chlorite often appears as a secondary mineral. It forms when minerals like biotite, hornblende, pyroxene, or garnet undergo alteration. For example, the glassy rims of pillow basalt on the ocean floor often turn into pure chlorite. This happens through the exchange of chemicals with seawater. Chlorite is also a common product of weathering and is found in many sedimentary rocks containing clay.

Chlorite-Group-Garnet-Group-65646
Chlorite-Group-Garnet-Group-65646

There are several distinct members within the chlorite group. The most common varieties are clinochlore, pennantite, and chamosite. Other named members include varieties like baileychlore, cookeite, and gonyerite. Some minerals have specific trade names based on their appearance. For instance, a massive, compact variety of clinochlore is known as seraphinite. This stone is used for decorative carving and is found in the Irkutsk Oblast of Eastern Siberia.

Chlorite schist
Chlorite schist

Other minerals in the group, such as donbassite and nimite, have been identified through scientific study over many decades.

While chlorite does not have major industrial uses, it does appear in specific applications. Some rocks containing chlorite, like chlorite schist, are used as construction stone. In the past, chlorite schist was quarried near Ely, Minnesota. It was used as roofing granules because its green color adhered well to asphalt shingles. Today, these are often replaced by synthetic materials. Beyond human use, chlorite is scientifically significant because it can be stable in the Earth's mantle. Experiments suggest it may exist in the mantle volume where island arc magmas are generated. This connects the mineral to the deep, complex processes of our planet's interior.

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File:Quartz-Chlorite-Group-139575.jpg
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File:Chlorite schist.jpg
Chlorite schist.jpg
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