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Linear molecular geometry

physical science Maturity 7-9 Next article →

Some tiny molecules form a straight line. This shape is called linear geometry.

Beryllium-fluoride-3D-vdW
Beryllium-fluoride-3D-vdW

In this shape, one central atom sits in the middle. Two other atoms sit on each side. They stay at a bond angle of 180 degrees. This means they form a perfectly straight line.

Why does this happen? Scientists use the VSEPR model to explain it. This model says that electron pairs push each other away.

AE2h
AE2h

In some molecules, three lone pairs sit around the center. Lone pairs are groups of electrons that stay near the atom. These pairs take up space. They push the two bonded atoms to opposite ends. This makes the molecule straight.

Many things have this shape. Beryllium fluoride has two single bonds. Carbon dioxide has two double bonds. Hydrogen cyanide has one single and one triple bond. Acetylene is a very important linear molecule. It has a triple bond and a single bond. Other examples include xenon difluoride and the triiodide ion. Even some ions, like nitronium, are linear.

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File:Beryllium-fluoride-3D-vdW.png
Beryllium-fluoride-3D-vdW.png
File:AE2h.svg
AE2h.svg
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