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Linear molecular geometry

physical science Maturity 7-9 Next article →

Some tiny molecules form a perfectly straight line. This shape is known as linear molecular geometry.

Beryllium-fluoride-3D-vdW
Beryllium-fluoride-3D-vdW

It happens when a central atom bonds to two other atoms. These other atoms are called ligands. They sit on opposite sides of the center. This creates a bond angle of 180 degrees. This straight shape is very important in science.

Scientists use the VSEPR model to explain this shape. VSEPR stands for Valence Shell Electron Pair Repulsion. This model shows how electron pairs push each other away.

AE2h
AE2h

In a linear shape, the central atom has two bonded atoms. It may also have zero or three lone pairs. Lone pairs are groups of electrons that stay near the atom. These pairs take up space and push the bonds away.

In some cases, the electron pairs form a specific shape. These five pairs form a shape called a trigonal bipyramid. The three lone pairs sit in equatorial positions. These are the middle spots that are less crowded. The two bonded atoms sit in axial positions. These are at the opposite ends of an axis. This setup forces the molecule to be straight.

Many different substances show this linear shape. Beryllium fluoride has two single bonds. Carbon dioxide uses two double bonds. Hydrogen cyanide has one single bond and one triple bond.

Beryllium-fluoride-3D-vdW
Beryllium-fluoride-3D-vdW

Acetylene is a very important example. Each carbon atom in it is a central atom. It has a single bond to hydrogen. It also has a triple bond to another carbon.

Other examples include many different types of ions. The azide and thiocyanate ions are linear anions. An anion is a particle with a negative charge. The nitronium ion is a linear cation. A cation is a particle with a positive charge. Xenon difluoride and the triiodide ion are also linear. These examples show how common this straight shape is in nature.

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File:Beryllium-fluoride-3D-vdW.png
Beryllium-fluoride-3D-vdW.png
File:AE2h.svg
AE2h.svg
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