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Bent molecular geometry

physical science Maturity 9-11 Next article →

Some tiny molecules are shaped like the letter V.

Oxygen-difluoride-3D-vdW
Oxygen-difluoride-3D-vdW

We call this bent molecular geometry. This means the parts do not sit in a straight line. Water is a famous example of this shape.

Oxygen-difluoride-3D-vdW
Oxygen-difluoride-3D-vdW

Why do they bend? It often happens because of lone pairs. These are extra bits of electrons that do not bond to other atoms. These lone pairs push on the bonds. This push makes the shape bend.

Most bent shapes have two bonds and two lone pairs. These molecules have angles between 104 and 109.5 degrees. The exact angle changes based on the other atoms. For example, nitrogen dioxide is also bent.

Oxygen-difluoride-3D-vdW
Oxygen-difluoride-3D-vdW

Other molecules have only one lone pair. These have a wider bend of about 120 degrees. One example is SnCl2. Some metals have bent shapes without any lone pairs. These have angles near 90 degrees. It is neat to see how these tiny parts work together.

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File:Oxygen-difluoride-3D-vdW.png
Oxygen-difluoride-3D-vdW.png
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