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Lead(II) acetate

physical science Maturity 11-13 Next article →

Lead(II) acetate is a white chemical that looks like crystals.

Lead(II)-acetate-xtal-Pb-coordination-3D-bs-17
Lead(II)-acetate-xtal-Pb-coordination-3D-bs-17

It has a slightly sweet taste. This chemical is a compound made of lead and an acetyl group. It can dissolve easily in water or glycerin. When it mixes with water, it becomes something called a trihydrate. This version is a white or colorless substance with a specific crystal shape.

Lead(II)-acetate-trihydrate-xtal-Pb-coordination-3D-noH-bs-17
Lead(II)-acetate-trihydrate-xtal-Pb-coordination-3D-noH-bs-17

Scientists use it as a reagent to make other lead compounds. It also helps dyes stick to fabrics and helps paints dry faster.

There are a few ways to make this substance. One way is to boil elemental lead in acetic acid and hydrogen peroxide. You can also use lead(II) oxide or lead(II) carbonate for this. Another way involves dissolving lead(II) oxide in acetic acid. You can even use a single-displacement reaction between copper acetate and lead metal.

Lead(II)-acetate-xtal-one-layer-3D-bs-17
Lead(II)-acetate-xtal-one-layer-3D-bs-17

The way the crystals are built changes depending on the form. The anhydrous version forms a 2D coordination polymer, which looks like flat sheets. The trihydrate version forms a 1D coordination polymer, which looks like long chains.

Lead(II)-acetate-trihydrate-xtal-chain-3D-noH-bs-17
Lead(II)-acetate-trihydrate-xtal-chain-3D-noH-bs-17

History shows that people used this chemical in many surprising ways. Because it tastes sweet, it was once used as a sugar substitute. Ancient Romans boiled grape juice in lead pots to make sweet syrups. They used these syrups to sweeten wine and preserve fruit.

Lead(II)-acetate-xtal-layers-3D-bs-17
Lead(II)-acetate-xtal-layers-3D-bs-17

People also used it in cosmetics and hair coloring dyes. A product called Grecian Formula used it for hair color until 2018. It was even used as a folk remedy for sore eyes by Meriwether Lewis in 1805. Mary Seacole also used it during a cholera epidemic in Panama.

Using this chemical has caused many serious problems. It causes lead poisoning, which is very dangerous to living things. Pope Clement II died in October 1047, possibly from eating sugar of lead. In 1787, a painter named Albert Christoph Dies swallowed some by accident. He lived with illnesses until he died in 1822. In 1887, thirty-eight horses in Dublin died after eating sweetened bran mash.

Lead(II)-acetate-trihydrate-xtal-packing-HB-3D-noH-bs-17
Lead(II)-acetate-trihydrate-xtal-packing-HB-3D-noH-bs-17

Even the famous composer Ludwig van Beethoven may have been harmed by it.

Today, we use lead(II) acetate for very specific tasks in science. Scientists use special paper to find a poisonous gas called hydrogen sulfide. When the gas touches the moistened paper, it turns grey. It can also be a byproduct when cleaning certain metal parts. Because it is so toxic, we must handle it with extreme care. Chemical facilities must dispose of it safely to protect people. We now use safer things, like bismuth citrate, instead of lead in many products.

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