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Cast iron

physical science Maturity 7-9 Next article →

Cast iron is a specific class of iron–carbon alloys. These alloys contain more than 2% carbon. They also typically contain between 1% and 3% silicon.

FeC-phase-diagram--multilingual
FeC-phase-diagram--multilingual

This material is highly valued in engineering. Its primary advantage is a relatively low melting temperature. This characteristic allows for excellent castability, which means the molten metal flows easily into molds. Cast iron also offers good machinability and high resistance to wear and deformation. Because of these traits, it is used for many essential items. These include pipes, machines, and automotive parts like cylinder blocks and gearbox cases.

Cast fe and cu dwv piping
Cast fe and cu dwv piping

The production of cast iron begins with pig iron. Pig iron is created by melting iron ore in a blast furnace. To create specific types of cast iron, this pig iron is often re-melted. During this melting process, workers add steel, limestone, and carbon, which is often called coke. They must also carefully remove undesirable contaminants. For example, phosphorus and sulfur can be burnt out of the molten iron. However, burning out these elements also removes carbon, so it must be replaced.

In-stream inoculation addition while molten cast iron is poured to a green sand mold in a foundry in Bangladesh
In-stream inoculation addition while molten cast iron is poured to a green sand mold in a foundry in Bangladesh

Engineers adjust the carbon and silicon levels to reach desired percentages. Carbon levels usually range from 2% to 3.5%. Silicon levels are typically between 1% and 3%. Modern production often uses electric induction furnaces or electric arc furnaces instead of a cupola.

The properties of cast iron change based on how the carbon appears in the metal. This is controlled by adding various alloying elements, or alloyants. Silicon is a vital alloyant because it forces carbon out of solution. If there is a low percentage of silicon, the carbon remains in solution as iron carbide. This creates white cast iron. If there is a high percentage of silicon, the carbon forms graphite. This results in grey cast iron.

Querschnitt Schalenhartguss
Querschnitt Schalenhartguss

Other elements like manganese, chromium, and molybdenum can counteract silicon. These elements promote the formation of carbides instead of graphite. Nickel and copper are often added to increase strength and machinability without changing the amount of graphite formed.

White cast iron is characterized by its hardness. The carbon precipitates out of the melt as a compound called cementite, or iron carbide. This makes the metal very hard but also very brittle. Because it is brittle, cracks can pass straight through the material easily.

Querschnitt Schalenhartguss
Querschnitt Schalenhartguss

Because it is difficult to cool thick pieces quickly enough to keep them entirely white, engineers sometimes create "chilled castings." These have a hard white iron surface and a tougher grey iron core. High-chromium white iron alloys are used for massive items like 10-tonne impellers. These alloys use chromium carbides to provide impressive abrasion resistance.

Grey cast iron is the most widely used type of cast iron by weight. It contains graphite flakes within its microstructure. These flakes help the material by deflecting passing cracks. When the metal breaks, these flakes initiate many tiny new cracks instead of one large failure. While grey iron has less tensile strength than steel, its compressive strength is comparable to low- and medium-carbon steel.

BLW Pair of firedogs
BLW Pair of firedogs

This makes it very useful for structures that must support heavy weight without being crushed.

Malleable and ductile cast irons offer more toughness. Malleable iron is produced by taking a white iron casting and heat-treating it. This process lasts for a day or two at specific temperatures. During this time, the iron carbide transforms into graphite and ferrite. The slow cooling allows the graphite to form into spheroidal particles.

Chengqiao artifact no. 35 cast iron
Chengqiao artifact no. 35 cast iron

Ductile cast iron, developed in 1948, is similar but more efficient for large parts. It uses tiny amounts of magnesium and cerium to create graphite in the form of very small, concentric nodules. These nodules act like a sponge, stopping cracks from progressing through the metal.

Humans have utilized cast iron for thousands of years. The earliest known artifacts date back to the 8th century BC. Archaeologists discovered these pieces in what is now Jiangsu, China.

Chengqiao artifact no. 35 cast iron
Chengqiao artifact no. 35 cast iron

In ancient China, it was used for agriculture, architecture, and mass-producing weapons. By the 15th century AD, cast iron was being used for shot and cannons in England and Burgundy, France. This required large-scale production methods. In the 1770s, Abraham Darby III built the first cast-iron bridge. This structure is known as the Iron Bridge and is located in Shropshire, England.

Iron Lion of Cangzhou 2007
Iron Lion of Cangzhou 2007
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🖼️ Images & Media (10)
File:In-stream inoculation addition while molten cast iron is poured to a green sand mold in a foundry in Bangladesh.jpg
In-stream inoculation addition while...
File:FeC-phase-diagram--multilingual.svg
FeC-phase-diagram--multilingual.svg
File:BLW Pair of firedogs.jpg
BLW Pair of firedogs.jpg
File:Querschnitt Schalenhartguss.jpg
Querschnitt Schalenhartguss.jpg
File:Chengqiao artifact no. 35 cast iron.png
Chengqiao artifact no. 35 cast iron.png
File:Eastern Han Blast Furnace Blower Model (10340434095).jpg
Eastern Han Blast Furnace Blower Model...
File:Iron Lion of Cangzhou 2007.jpg
Iron Lion of Cangzhou 2007.jpg
File:Cast fe and cu dwv piping.jpg
Cast fe and cu dwv piping.jpg
File:Fluegel-Rahmen.jpg
Fluegel-Rahmen.jpg
File:Belgian waffles cooked in a Krampouz cast-iron waffle iron.JPG
Belgian waffles cooked in a Krampouz...
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