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Metal

physical science Maturity 9-11 Vital Level 3 Next article →

A metal is a material characterized by specific physical and chemical properties. When polished or fractured, metals often show a lustrous or shiny appearance. They are also excellent conductors of both electricity and heat. These characteristics are not accidental. They occur because metals have electrons available at the Fermi level. This means certain electrons are in a state where they can easily move and interact with energy.

Band filling diagram
Band filling diagram

A metal can be a single chemical element, like iron, or a mixture called an alloy, such as stainless steel. It can even be a molecular compound, like polymeric sulfur nitride.

The way metals conduct electricity is a result of their unique electronic structure. In most materials, electrons are stuck in specific energy levels. In metals, however, there are unoccupied, delocalized electron states near the highest occupied levels. When a voltage is applied, some electrons shift to states with slightly higher momentum in the direction of the electric field. This creates a net drift velocity, which we recognize as an electric current.

Band filling diagram
Band filling diagram

This conduction happens even at absolute zero because of these delocalized states. In contrast, semiconductors have an energy gap that prevents easy electron flow.

Metals also move heat very efficiently through a process called conduction. This heat is transported mainly by the conduction electrons. As these electrons gain kinetic energy, they can pass that thermal energy to other parts of the material. The Wiedemann–Franz law describes a relationship in many metals where the ratio of thermal conductivity to electrical conductivity is proportional to the temperature.

TiN DOS
TiN DOS

Generally, as a metal heats up, its electrical conductivity decreases. This happens because the increased thermal motion of the atoms makes it harder for the electrons to flow smoothly.

Physical shaping is another defining trait of metals, described by two terms: malleability and ductility. Malleable metals can be hammered or pressed into sheets. Ductile metals can be drawn out into thin wires.

Ductility
Ductility

This ability to deform without breaking is due to the nondirectional nature of metallic bonding. This allows for dislocation motion, where atoms can slide past one another. In many metals, the atoms are arranged in close-packed crystal structures. These include body-centered cubic (bcc), face-centered cubic (fcc), and hexagonal close-packed (hcp) structures.

Gallium crystals
Gallium crystals

There is a massive range in the density of different metals. Density measures how much mass is packed into a specific volume. Lithium is the least dense metal, with a density of only 0.534 g/cm3. On the other end of the scale, osmium is the most dense at 22.59 g/cm3.

Gallium crystals
Gallium crystals

Many industrial metals are chosen because they are lightweight. For example, aluminum has a density of 2.7 g/cm3, which is much lighter than iron at 7.9 g/cm3. Magnesium and titanium are also important light metals used in many modern applications.

The history of human interaction with metals spans many millennia. Humans likely began using copper about 11,000 years ago. Before the first bronze appeared in the fifth millennium BCE, people used gold, silver, lead, and even meteoric iron.

Netuno19b
Netuno19b

The discovery of sodium in 1809 marked the finding of the first light metal. Since the end of World War II, scientists have developed increasingly sophisticated alloys for specialized uses.

Sauce boat
Sauce boat

Today, metals are essential to almost every aspect of modern civilization. Their strength and resilience make them vital for high-rise buildings and large bridges. They are used to construct vehicles, tools, pipes, and railroad tracks.

CompactedSteelScraps
CompactedSteelScraps

In the electronics industry, multi-element metals like titanium nitride are used in semiconductors. Even our money relies on them; modern coinage includes at least 23 different chemical elements. From the stainless steel in a gravy boat to the heavy structural steel in a skyscraper, metals shape our world.

Sauce boat
Sauce boat
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🖼️ Images & Media (24)
File:Iron electrolytic and 1cm3 cube.jpg
Iron electrolytic and 1cm3 cube.jpg
File:Sauce boat.jpg
Sauce boat.jpg
File:Gallium crystals.jpg
Gallium crystals.jpg
File:Ductility.svg
Ductility.svg
File:Band filling diagram.svg
Band filling diagram.svg
TiN_DOS.tif
File:Battery Demonstration Unit - DPLA (cropped).jpg
Battery Demonstration Unit - DPLA (cropped).jpg
File:Pigs and Bars of Babbitt.jpg
Pigs and Bars of Babbitt.jpg
File:Willem Lenssinck - Formula I Racing Horse.jpg
Willem Lenssinck - Formula I Racing Horse.jpg
File:Rhodium powder pressed melted.jpg
Rhodium powder pressed melted.jpg
File:Titanium nitride coating 90.jpg
Titanium nitride coating 90.jpg
File:Conducting polymers.svg
Conducting polymers.svg

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