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Bastnäsite

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Bastnäsite is a significant group of fluorocarbonate minerals that serve as primary sources for rare-earth elements.

Bastnasite-155010
Bastnasite-155010

These minerals are essential because they contain lanthanides, which are a group of chemical elements used in many modern technologies. There are three main types of bastnäsite, categorized by which rare-earth element is most abundant in their structure. The first is bastnäsite-(Ce), which is dominated by cerium. The second is bastnäsite-(La), which contains more lanthanum. The third is bastnäsite-(Y), which is characterized by a higher amount of yttrium.

Bastnaesite crystal structure
Bastnaesite crystal structure

Most natural specimens belong to the cerium variety, making it the most common form found in nature.

The chemical structure of these minerals determines their specific classification. Bastnäsite-(Ce) has the chemical formula (Ce, La)CO3F. Bastnäsite-(La) follows the formula (La, Ce)CO3F. Finally, bastnäsite-(Y) is expressed as (Y, Ce)CO3F. Some variations exist where fluoride (F−) ions are replaced by hydroxyl (OH−) ions. These specific minerals are known as hydroxylbastnäsite. The mineral is also closely related to a series called parisite. Parisite is also a rare-earth fluorocarbonate, but it contains calcium and a different ratio of ions. In nature, bastnäsite and parisite can actually alter back and forth by adding or losing calcium carbonate (CaCO3).

Extracting useful metals from bastnäsite ore involves a complex, multi-step industrial process.

Pyrometallury for rare earth metal extraction from bastnasite ore
Pyrometallury for rare earth metal extraction from bastnasite ore

The process typically begins with comminution, where the ore is ground into a fine powder using rod or ball mills. Next, chemicals like soda ash fluosilicate are added to coat the rare-earth metals. This prepares them for flotation, a method used to separate the valuable minerals from the surrounding waste rock, known as gangue. Once the concentrate is collected, it is filtered and heated to approximately 100 °C to remove excess water. To make the metals soluble, hydrochloric acid (HCl) is added to lower the pH to less than 5. This allows elements like cerium to dissolve into a liquid solution.

After the metals are dissolved, they must be separated from one another through advanced chemical techniques. An oxidizing roast is often used to concentrate the solution to about 85% rare-earth oxides (REO). Scientists then use solvent extraction to isolate specific elements. This involves adding different solvents to capture individual metals like europium (Eu), samarium (Sm), or gadolinium (Gd). For example, lanthanum can be collected by adding nitric acid (HNO3) to create lanthanum nitrate, or by using hydrochloric acid to create lanthanum chloride. These steps allow industries to produce high-purity individual metals or specific lanthanide mixes for various manufacturing needs.

The history of bastnäsite is deeply tied to the discovery of the periodic table.

Bastnasite-(Ce)-177535
Bastnasite-(Ce)-177535

The mineral was first described in 1838 by the Swedish chemist Wilhelm Hisinger. He named it after the Bastnäs mine in Västmanland, Sweden, where he was the owner. This specific mine was a site of immense scientific importance. It led to the discovery of several new chemical elements by Swedish scientists. Hisinger himself described the element cerium in 1803. Later, in 1839, the element lanthanum was also identified through research related to these types of ores.

Bastnäsite deposits are found in diverse geological settings across the globe. It occurs in alkali granite, syenite, and carbonatites, which are rare types of igneous rocks. Significant deposits have been identified in many locations, including Norway, Russia, Canada, and Pakistan. In the United States, the Mountain Pass mine in California is a famous site. Discovered in 1949, Mountain Pass became a major global source of lanthanides from the 1960s through the 1980s. Today, China is a dominant supplier, particularly through the massive Bayan Obo deposit in Inner Mongolia. This site provides the majority of the world's lanthanides as of 2008.

The economic and technological significance of bastnäsite cannot be overstated. The ore from the Mountain Pass mine was particularly valuable due to its europium content. The ore contained about 0.1% europium oxide, which was essential for the color television industry. This metal provided the red phosphor necessary to create bright, clear images on screens. The lanthanide composition of Mountain Pass ore included approximately 49% cerium, 33% lanthanum, 12% neodymium, and 5% praseodymium. Because these elements are vital for high-tech components, bastnäsite remains one of the most important industrial mineral resources in the world.

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File:Radioactive.svg
Radioactive.svg
File:Bastnasite-155010.jpg
Bastnasite-155010.jpg
File:Bastnaesite crystal structure.png
Bastnaesite crystal structure.png
File:Bastnasite-(Ce)-177535.jpg
Bastnasite-(Ce)-177535.jpg
File:Pyrometallury for rare earth metal extraction from bastnasite ore.jpg
Pyrometallury for rare earth metal...
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