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Monazite

earth science Maturity 7-9 Next article →

Monazite is a group of reddish-brown phosphate minerals.

Monazit - Madagaskar
Monazit - Madagaskar

These minerals are highly valued because they contain rare-earth elements. Because the chemical makeup of these minerals can change, scientists classify them as a group rather than a single species. The most common member is monazite-(Ce). This name indicates that cerium is the dominant element in its composition.

Monazite is essential for modern industry. It serves as a primary ore for elements like lanthanum, cerium, and thorium. These elements are used in many different technologies around the world.

The internal structure of monazite is quite specific. All monazites share the same basic structural motif. In this structure, the M(III) centers have a distorted coordination sphere. This means they are surrounded by eight oxides. The distance between these atoms is approximately 2.6 Å. The phosphate anion within the structure is tetrahedral.

PbCrO4
PbCrO4

This structure is very similar to other minerals like zircon, xenotime, and barite. This shared connectivity helps scientists understand how different minerals are built at an atomic level.

Scientists categorize monazite into five common species. These types are determined by the relative amounts of rare-earth elements present. The five most common are monazite-(Ce), monazite-(La), monazite-(Nd), monazite-(Sm), and monazite-(Gd). In monazite-(Ce), cerium is the most abundant. In monazite-(La), lanthanum is the most common element. The element listed in the parentheses tells you which rare-earth element is the most prevalent. This classification allows researchers to predict the chemical properties of a specific sample.

Extracting these valuable metals requires complex chemical processes. One traditional method is called acid cracking. In this process, the mineral is heated with concentrated sulfuric acid for several hours.

Monazite acid cracking process
Monazite acid cracking process

This heat and acid break the mineral apart. One variation causes thorium to precipitate out as a crude phosphate. This leaves a solution of lanthanide sulfates behind. A more modern method is known as alkaline cracking. This process uses a hot sodium hydroxide solution at about 500 °C.

Monazit opening alkaline
Monazit opening alkaline

This method is useful because it allows the phosphate to be recovered as crystalline trisodium phosphate.

The history of monazite is tied to the birth of the rare-earth industry. In the 1880s, Carl Auer von Welsbach noticed monazite sand in ship ballast from Brazil. He was searching for thorium to create incandescent mantles for light bulbs.

monazitemineshelbync
monazitemineshelbync

This discovery quickly made monazite sand the foundation of the rare-earth industry. In 1904, T. H. Laby and Douglas Mawson discovered radium-bearing ore in Australian monazite. They analyzed samples from the Pilbara region at the University of Sydney. These findings provided early insights into the radioactive nature of these minerals.

Monazite is often found in placer deposits. These are heavy sands formed when minerals are released by the weathering of pegmatites. These deposits are frequently found on beaches or fossil beaches.

Monazit - Madagaskar
Monazit - Madagaskar

India, Madagascar, and South Africa contain large deposits. The sands in India are noted for being particularly rich. Monazite is a heavy mineral, which allows it to be separated using gravity, magnetic, or electrostatic methods. The mineral has a specific gravity of 5.0 to 5.5. It also has a hardness of 5.0 to 5.5 on the Mohs scale.

Because monazite contains thorium and uranium, it is radioactive. This property is useful for a field called monazite geochronology. As uranium and thorium undergo alpha decay, they turn into lead.

Radioactive
Radioactive

By measuring this decay, scientists can date the geologic history of host rocks. Monazite crystals often have distinct zones from different geologic events. These zones allow researchers to see how the rock changed over time. Furthermore, monazite is being studied as a way to store nuclear waste. Researchers at Oak Ridge National Laboratory found that synthetic monazite resists corrosion better than borosilicate glass. It can remain crystalline even after being subjected to high amounts of radiation.

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🖼️ Images & Media (8)
File:Radioactive.svg
Radioactive.svg
File:PbCrO4.jpg
PbCrO4.jpg
File:monazitemineshelbync.jpg
monazitemineshelbync.jpg
File:MonaziteUSGOV.jpg
MonaziteUSGOV.jpg
File:Monazit - Madagaskar.jpg
Monazit - Madagaskar.jpg
File:Monazite acid cracking process.svg
Monazite acid cracking process.svg
File:Monazit opening alkaline.gif
Monazit opening alkaline.gif
File:Hydrometallury of rare earth metals from monazite ore process flow diagram.jpg
Hydrometallury of rare earth metals from...
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