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Apatite

earth science Maturity 7-9 Next article →

Apatite is a diverse group of phosphate minerals that play a vital role in both geology and biology. This group is defined by its chemical structure, which consists of calcium and phosphate. The specific type of apatite depends on which ions are held within its crystal structure. The three most common members are hydroxyapatite, fluorapatite, and chlorapatite. These names come from the presence of hydroxide, fluoride, or chloride ions, respectively. Because these minerals are so versatile, they are found in many different environments on Earth and even on the Moon.

Thin section microscopy Siilinjärvi R301 6170 apatite
Thin section microscopy Siilinjärvi R301 6170 apatite

The chemistry of apatite is driven by the way different ions fit into its crystal unit cell. The general formula for a mixture of the three main types is Ca10(PO4)6(OH,F,Cl)2. Each individual mineral has its own specific formula. For example, hydroxyapatite is written as Ca10(PO4)6(OH)2. Fluorapatite is written as Ca10(PO4)6F2, and chlorapatite is written as Ca10(PO4)6Cl2. These small changes in the ions present can change how the mineral behaves. Fluorapatite is notably more resistant to acid than hydroxyapatite. This chemical resilience is why fluoride is used to protect human teeth.

Apatite taillée
Apatite taillée

Apatite appears in many different geological settings. It is the most common phosphate mineral in both igneous and metamorphic rocks. In these rocks, it often appears as very small grains. These grains are sometimes only visible when viewed through a thin section under a microscope.

Thin section microscopy Siilinjärvi R301 6170 apatite
Thin section microscopy Siilinjärvi R301 6170 apatite

Larger, coarse crystals are usually found in specific environments like pegmatites or marble. Apatite can also be found in sedimentary rocks. This happens when grains are eroded from their original source rock. Sometimes, apatite forms when animal skeletons break down or when it precipitates from seawater onto fish scales. In some cases, it forms rocks called phosphorite, which can contain as much as 80% apatite.

The history of the mineral's name is quite unique. The German geologist Abraham Gottlob Werner named it in 1786. He chose the name from the Greek word "apatáō," which means "to deceive." He gave it this name because mineralogists had repeatedly misclassified it as other minerals, such as aquamarine. In 1860, the German mineralogist Karl Friedrich August Rammelsberg reclassified the specific mineral Werner had described as fluorapatite. This helped clear up the confusion that led to the "deceiver" nickname. Today, we understand the distinct chemical differences that once caused such mistakes.

In biology, apatite is essential for vertebrate animals. Hydroxyapatite is the primary component of bone mineral and tooth enamel. A rarer form of apatite is also found in bone material. This version contains many carbonate and acid phosphate substitutions and lacks most hydroxide groups. Humans can use chemistry to interact with this biological apatite. When we use fluoridated water or toothpaste, fluoride ions can exchange with the hydroxyl groups in our teeth. This process helps strengthen the enamel against acid. However, scientists note that too much fluoride can lead to dental or skeletal fluorosis.

Apatite taillée
Apatite taillée

Apatite has many important industrial and economic uses. Its primary use is as a source of phosphate for making fertilizer. It is also used as an ore for rare-earth elements. Because apatite is not very radioactive, it is often preferred over traditional rare-earth ores like monazite. It can also be a source of uranium and vanadium. In the past, a specific type of apatite was used in the phosphor system for fluorescent tubes. While that system is now obsolete, apatite has a long history of use in pigments. For instance, ground apatite was used as a pigment for the Terracotta Army in China.

Siilinjärvi Särkijärvi pit
Siilinjärvi Särkijärvi pit

Beyond Earth, apatite provides clues about the history of our solar system. Apollo program astronauts collected moon rocks that contain traces of apatite. In 2010, a re-analysis of these samples revealed something surprising. The apatite contained water trapped as hydroxyl within the mineral. This discovery showed that the Moon has much more water than scientists previously estimated. The amount of water could be as high as 5 parts per million. If all this mineral-locked water were turned into liquid, it could cover the Moon's surface in about one meter of water.

Siilinjärvi Särkijärvi pit
Siilinjärvi Särkijärvi pit
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File:Apatite taillée.jpg
Apatite taillée.jpg
File:Thin section microscopy Siilinjärvi R301 6170 apatite.jpg
Thin section microscopy Siilinjärvi R301...
File:Siilinjärvi Särkijärvi pit.jpg
Siilinjärvi Särkijärvi pit.jpg
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