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Aqua regia

physical science Maturity 11-13 Next article →

Aqua regia is a very strong liquid used by scientists. Its name comes from Latin and means "royal water."

Aqua regia in NMR tubes
Aqua regia in NMR tubes

This liquid is special because it can dissolve noble metals. These are metals like gold and platinum that usually do not react with other things. Most acids cannot break these metals down. However, aqua regia is powerful enough to turn solid gold into a liquid.

Aqua regia in Davenport Laboratories
Aqua regia in Davenport Laboratories

This makes it a very important tool for chemistry.

To make this liquid, you mix two different acids together. You use concentrated nitric acid and concentrated hydrochloric acid. The best mix uses a ratio of one part nitric acid to three parts hydrochloric acid.

Aqua regia
Aqua regia

When they mix, a chemical reaction happens right away. This reaction creates gases like nitrosyl chloride and chlorine gas. Because of these gases, the liquid starts to fume. It also changes color from clear to yellow, orange, or red within seconds. As the gases escape, the liquid loses its strength. This is why scientists usually mix it right before they need to use it.

People have known about this liquid for a very long time. Records from 660 AD show that nitrate was used to make it. In Europe, it appeared in old books written by people like pseudo-Geber. Early alchemists used it to work with gold. They even used art to describe it. One old drawing shows a fox eating a rooster. The rooster represents gold, and the fox represents the aqua regia.

This shows how much they wondered about its power.

Today, aqua regia has many important jobs in science. It is used in the Wohlwill process to make very pure gold. This process can make gold that is 99.999% pure.

Golddust
Golddust

Scientists also use it to clean glassware in laboratories. It is great for cleaning NMR tubes because it leaves no metal traces behind. It can even help find new metals. When scientists used it on platinum, they discovered two very dense metals called iridium and osmium. These metals did not dissolve and stayed at the bottom of the container.

This liquid has even played a part in world history. During World War II, a chemist named George de Hevesy used it to hide treasure. He dissolved two gold Nobel Prize medals in aqua regia. He did this so the Nazis would not take them. He put the liquid on a shelf in his lab. The soldiers did not realize the gold was hidden in the jar. After the war ended, de Hevesy recovered the gold from the acid. The medals were then remade and given to the winners again.

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🖼️ Images & Media (5)
File:Aqua regia.svg
Aqua regia.svg
File:Aqua regia in Davenport Laboratories.jpg
Aqua regia in Davenport Laboratories.jpg
File:Aqua regia in NMR tubes.jpg
Aqua regia in NMR tubes.jpg
File:Golddust.jpg
Golddust.jpg
Musaeum Hermeticum 1678 p 398 III. Clavis AQ27.tif
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