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Tarnish

physical science Maturity 11-13 Next article →

Metals often change color on their surface. This thin layer is called tarnish. It is a form of corrosion. Tarnish forms on metals like copper and brass. It also forms on aluminum, magnesium, and neodymium. This happens because the outermost layer of the metal undergoes a chemical reaction.

Wolfram evaporated crystals and 1cm3 cube
Wolfram evaporated crystals and 1cm3 cube

Tarnish usually looks like a dull film. It may appear gray or black. It is a surface phenomenon. This means it only affects the very top of the metal.

Tarnish works in a special way. It is self-limiting. This is different from rust. Rust can spread deep into the metal. Tarnish only reacts with the top few layers. This layer actually seals the metal. It protects the layers underneath from more reactions. When this happens outdoors, it is called a chemical patina. One example is verdigris. This is a green or blue-green layer on copper. It is made of copper(II) carbonate.

1899 reverse
1899 reverse

Chemistry explains how tarnish forms. It is a chemical change. It happens when a metal meets a nonmetal compound. Oxygen and sulfur dioxide are common causes. The reaction often creates a metal oxide. This process is called oxidation. Sometimes the reaction creates a metal sulfide instead. The metal oxide can also react with other things. It might react with water to make a hydroxide. It can also react with carbon dioxide to make a carbonate.

People have different views on tarnish. Some people think it looks bad. They may want to clean silverware. Other people think it is beautiful. Collectors might like the toning on old coins. This toning can add value to a coin.

1899 reverse
1899 reverse

Heavy tarnish can be removed with tools. You might use a file or sandpaper. Steel wool and emery paper also work. For light tarnish, people use baking soda. Museums use very gentle things. They use calcium carbonate to clean silver. This keeps the metal safe from scratches.

There are even clever ways to clean metal. You can use a method called electrochemical cleaning. This is a way to reverse tarnish without damage. You can use a pot of boiling water. Place the silver on a piece of aluminum foil. Add a small amount of salt or baking soda. This process helps clean the object safely.

Wolfram evaporated crystals and 1cm3 cube
Wolfram evaporated crystals and 1cm3 cube

It shows how science helps us care for our things. You can see these changes in many places around you.

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