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Solder

technology Maturity 11-13 Next article →

Solder is a fusible metal alloy used to create permanent bonds between metal workpieces.

Solder on spool
Solder on spool

This material is vital for many industries, including electronics, plumbing, and sheet metal work. To function correctly, a solder must have a lower melting point than the metal parts it is joining. It must also resist oxidative and corrosive effects to prevent the joint from degrading over time. For electrical applications, the alloy must also possess favorable electrical characteristics to carry current effectively.

The soldering process begins by heating the metal parts to be joined. The solder is then melted so that it can "wet" the surfaces. Wetting occurs when the liquid metal adheres to and connects the pieces. As the metal cools, it solidifies into a permanent bond.

Solderedjoint
Solderedjoint

Some alloys are described as eutectic. A eutectic alloy has the lowest possible melting point for its specific mixture. In these alloys, the melting point coincides exactly with the freezing point. This means the metal transitions from liquid to solid at a single, specific temperature.

Non-eutectic alloys behave differently because they have distinct solidus and liquidus temperatures. This creates a range between the temperature where melting starts and where it ends. During this transition, the alloy may exist as a pasty state, consisting of solid particles in a melted matrix.

60-40 Solder
60-40 Solder

In electrical work, disturbing a joint while it is in this pasty state can result in a poor connection. However, plumbers can exploit this state to create a "wiped joint." This involves molding the solder during cooling to ensure a pipe joint is completely watertight.

Propane torch soldering copper pipe
Propane torch soldering copper pipe

Historically, alloys of lead and tin were the standard for soldering. These were very convenient for manual work using a soldering iron or a soldering gun. However, lead is a potent neurotoxin that can be harmful to human health. In the United States, the Safe Drinking Water Act has prohibited lead in plumbing solder for drinking water since 1974. While lead-based solder was used in plumbing until the 1980s, it was eventually replaced by silver or antimony to protect public health. Today, lead-free solders are used almost exclusively in consumer electronics due to global regulatory requirements, such as those in the European Union.

Modern lead-free solders often use combinations of tin, silver, copper, bismuth, indium, zinc, or antimony.

Pure tin solder
Pure tin solder

A popular family of these alloys is Tin-silver-copper, also known as SAC. Researchers from Ames Laboratory and Sandia National Laboratories discovered and patented the ternary eutectic behavior of SAC. This specific mixture is widely used because it has a relatively low melting point for a lead-free option. Different diameters of solder wire are also used depending on the task. Ultra-fine wires (0.25 mm to 0.5 mm) are for micro soldering. Heavy gauge wires (1.5 mm to 2.0 mm and above) are used for large electrical connections or plumbing.

Different metals are added to alloys to change their specific properties. Antimony is added to increase strength without affecting how well the metal wets a surface. Bismuth is used to significantly lower the melting point and improve wetting. However, bismuth can form crystals that may cause a joint to fail at low temperatures if lead and tin are present. In jewelry making, specialized "hard solders" are used. These are categorized by hardness, ranging from "enameling" to "repair" grades.

Silver solder
Silver solder

Silver solders can contain up to 40% silver and are used to join parts that cannot be welded.

Gold solder
Gold solder

Soldering also involves complex chemical interactions with other metals. For example, tin-based solders can readily dissolve gold plating, which forms brittle intermetallic joins. If a joint is soldered to gold for a long time, the tin surface may appear very dull. Additionally, some solders contain small amounts of radioisotope impurities. Polonium-210 is a specific concern because it is an intense emitter of alpha particles. Understanding these chemical and thermal properties allows engineers to choose the exact right alloy for every technological need.

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🖼️ Images & Media (8)
File:Solder on spool.jpeg
Solder on spool.jpeg
File:Solderedjoint.jpg
Solderedjoint.jpg
File:60-40 Solder.jpg
60-40 Solder.jpg
File:Pure tin solder.JPG
Pure tin solder.JPG
File:Propane torch soldering copper pipe.jpg
Propane torch soldering copper pipe.jpg
File:Silver solder.jpg
Silver solder.jpg
File:Gold solder.jpg
Gold solder.jpg
File:Rosin core electrical solder.JPG
Rosin core electrical solder.JPG
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