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Peroxide

physical science Maturity 11-13 Next article →

Peroxides are a special group of molecules. They are important because they have a unique structure. This structure features a peroxy group. This group contains two oxygen atoms joined together. These oxygen atoms are connected by a single covalent bond. A covalent bond is a way atoms stay linked. This linkage is a common polyatomic ion. It exists in many different molecules.

Peroxide group v.2
Peroxide group v.2

Let us look at how these molecules work. The two oxygen atoms share a single covalent bond. This bond connects the two main atoms together. Each oxygen atom has an oxidation state of negative one. This happens because five of its valence electrons stay in the outer shell. One more electron is used in the covalent bond. This means each atom has seven valence electrons. This arrangement gives the oxygens a negative charge.

Peroxide group v.2
Peroxide group v.2

People have studied these molecules for a long time. A scientist named Thomas Thomson introduced the term. He did this in the year 1804. He used the name for a specific type of compound. This compound had as much oxygen as possible. It was the oxide with the largest amount of oxygen. The way we name these groups can sometimes vary. This is because of how they were first discovered.

Peroxide group v.2
Peroxide group v.2

There are many different kinds of peroxides. Hydrogen peroxide is the most common form. Most people just call it "peroxide." Other types include peroxy acids like peracetic acid. You might also find peroxymonosulfuric acid. Some peroxides are made with metals. Examples include barium peroxide, sodium peroxide, and zinc peroxide. There are also organic peroxides. One example is tert-butylhydroperoxide.

Peroxide group v.2
Peroxide group v.2

All peroxides change based on what they are joined to. The properties and structure change when other elements are added. This charge is affected by those extra elements. You can think of the peroxy group like a building block. You can add different pieces to change the whole shape. Main group peroxides use a main group element for their linkage. Organic peroxides use a hydrocarbon moiety. This makes the world of chemistry very diverse.

Peroxide group v.2
Peroxide group v.2
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