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Neon compounds

physical science Maturity 11-13 Next article →

Neon is a very special gas from the periodic table. For a long time, scientists believed neon could not make compounds. A compound is what happens when different atoms join together. Neon is actually the least reactive of all the elements. It has a very high first ionization potential of 21.564 eV. This means it takes a huge amount of energy to pull an electron away. Because of this, it is very hard to make stable ionic compounds with neon.

Even though neon is quiet, it can still stick to other things. It can form what are called Van der Waals molecules. In these molecules, neon is held by very weak London dispersion forces. These forces are so tiny that heat can easily break them apart. If the temperature gets too high, the bonds will be disrupted. Neon atoms can also link together to make small clusters. Scientists have used Coulomb explosion imaging to see these clusters. They found the neon dimer, trimer, and tetramer.

Scientists have learned a lot about these tiny shapes over time. The neon dimer has an average distance of 3.3 Å between its atoms. The neon trimer looks like an equilateral triangle. However, this shape is floppy and can look like an isosceles triangle. The neon tetramer takes the shape of a tetrahedron with sides around 3.2 Å. These discoveries show that even a quiet gas has many shapes. Researchers use supersonic jets of neon gas to make these molecules.

Neon can also be trapped in tiny cages called fullerenes. These are small balls made of carbon, like the C60 buckyball. To get neon inside, scientists heat buckminsterfullerene to 600 °C under pressure. They use three atmospheres of pressure for one hour. Only about 1 in 8,500,000 molecules actually end up with neon inside. This neon stays inside until it is heated to 900 °C. We also find neon in space within carbonaceous chondrite meteorites. These rocks have much more of the isotope 22Ne than Earth does.

Neon can also act as a ligand in chemistry. A ligand is a molecule that attaches to a central metal atom. Neon can form very weak bonds with metals like chromium, molybdenum, and tungsten. It can even form ions, which are atoms with an electric charge. For example, the copper ion Cu+ can hold up to 24 neon atoms. Scientists also study excimers, which are temporary molecules in an excited state. These are used in special lamps to create light.

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