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Manganese

physical science Maturity 7-9 Next article →

Manganese is a chemical element with the symbol Mn and atomic number 25. It is a transition metal characterized by a hard, silvery-gray appearance that resembles iron.

ManganeseOreUSGOV
ManganeseOreUSGOV

Despite its strength, manganese is very brittle and difficult to melt. It often occurs in nature in combination with iron. This element is vital to modern industry and biological life. It serves as a critical component in many chemical reactions and biological systems.

Spiegeleisen
Spiegeleisen

In industrial settings, manganese is most famous for its role in metallurgy. It is a key ingredient in the production of stainless steel. When added to steel, manganese improves its strength and workability. It also increases the metal's resistance to wear. Beyond steel, manganese oxide acts as an oxidizing agent. This means it helps drive chemical reactions that involve oxygen. Manganese oxide is also used in making glass, ceramics, and fertilizers.

Manganese Process Flow Diagram
Manganese Process Flow Diagram

Manganese can exist in several different structural forms, known as allotropes. These forms change depending on the temperature. Alpha manganese (α-Mn) is the stable form at room temperature. It has a very complex crystal structure with 58 atoms per unit cell.

Alpha-Mn
Alpha-Mn

When heated, it transforms into beta manganese (β-Mn). This form has a primitive cubic structure with 20 atoms per unit cell.

Beta-Mn
Beta-Mn

If heated even further, it becomes gamma manganese (γ-Mn), which has a simpler structure. Finally, delta manganese (δ-Mn) forms at high temperatures and remains stable until the metal melts at 1,246 °C.

Phase diagram of manganese (1975)
Phase diagram of manganese (1975)

The history of manganese is tied to ancient human activity. Long ago, people used manganese dioxide as a dark pigment. This mineral was used to create cave paintings, such as those found in Lascaux, France.

Lascaux painting
Lascaux painting

Later, Egyptian and Roman glassmakers used manganese to change the color of glass. In the 16th century, glassmakers called the substance "manganesum." The metal itself was first isolated in the 1770s. Many historians credit the Swedish chemist Johan Gottlieb Gahn with this discovery.

Gahn Johan Gottlieb
Gahn Johan Gottlieb

In the human body, manganese is an essential dietary element. It is necessary for macronutrient metabolism and bone formation. It also helps the body's free radical defense systems.

The Searchlight Rhodochrosite Crystal
The Searchlight Rhodochrosite Crystal

Most manganese in humans is stored in the bones. Smaller amounts are found in the liver, kidneys, and brain. In the brain, manganese binds to specific proteins called metalloproteins. One notable example is glutamine synthetase, which is found in cells called astrocytes. Manganese is also a key part of the oxygen-evolving complex in plants, which helps produce oxygen.

Scientists study manganese through its many different oxidation states. These states represent the different ways manganese can lose or gain electrons. Common states include +2, +3, +4, +6, and +7. For example, manganese in the +7 state forms potassium permanganate. This is a deep violet salt used frequently in laboratories as an oxidizer.

KMnO4 in H2O
KMnO4 in H2O

In aqueous solutions, the +2 state is very common and appears pale pink.

Chlorid manganatý
Chlorid manganatý

Other forms, like the green manganate ion, represent the +6 oxidation state. Even the common ore pyrolusite is a form of manganese in the +4 state.

On a cosmic scale, manganese has a fascinating origin. It belongs to the iron group of elements. Scientists believe these elements are synthesized inside massive stars. This happens just before a star ends its life in a supernova explosion.

Dendrites01
Dendrites01

Manganese also has several isotopes, which are different versions of the element. Naturally occurring manganese is mostly composed of the stable isotope 55Mn. Other isotopes, like 53Mn, are radioactive and decay over time. By studying the ratios of manganese to chromium in meteorites, researchers can learn about the history of our early Solar System.

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🖼️ Images & Media (18)
File:Alpha-Mn.png
Alpha-Mn.png
File:Beta-Mn.png
Beta-Mn.png
File:Phase diagram of manganese (1975).png
Phase diagram of manganese (1975).png
File:Chlorid manganatý.JPG
Chlorid manganatý.JPG
File:KMnO4 in H2O.jpg
KMnO4 in H2O.jpg
File:Lascaux painting.jpg
Lascaux painting.jpg
File:Gahn Johan Gottlieb.jpg
Gahn Johan Gottlieb.jpg
File:ManganeseOreUSGOV.jpg
ManganeseOreUSGOV.jpg
File:Mineraly.sk - psilomelan.jpg
Mineraly.sk - psilomelan.jpg
File:Spiegeleisen.jpg
Spiegeleisen.jpg
File:Dendrites01.jpg
Dendrites01.jpg
File:The Searchlight Rhodochrosite Crystal.jpg
The Searchlight Rhodochrosite Crystal.jpg

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