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Latent heat

physical science Maturity 9-11 Next article →

Latent heat is a specific form of energy transferred during a constant-temperature process. It is often called latent energy or the heat of transformation. This energy is absorbed or released when a substance undergoes a phase change. A phase change is a transition between states of matter, such as solid, liquid, or gas. Unlike sensible heat, which causes a measurable change in temperature, latent heat does not change the temperature or pressure of a system.

Black Joseph (cropped)
Black Joseph (cropped)

Instead, this energy is used to change the physical state of the substance. Because the temperature remains steady during the transition, the energy is often described as "hidden."

To understand the mechanism, we must look at how particles interact. When a substance undergoes an endothermic process, it absorbs energy. For example, during vaporization, water molecules must absorb energy to overcome the forces of attraction between them. This allows them to break free from the liquid state and become a gas. During this entire process, the temperature of the water does not rise. The energy is entirely dedicated to the phase change. Conversely, when vapor condenses into a liquid, it releases this stored energy. This released energy is then felt as sensible heat on the surface where condensation occurs.

Heat of Vaporization (Benzene+Acetone+Methanol+Water)
Heat of Vaporization (Benzene+Acetone+Methanol+Water)

Scientists categorize latent heat into several distinct types based on the direction of the phase change. The latent heat of fusion refers to the energy involved when a solid melts into a liquid or a liquid freezes into a solid. The latent heat of vaporization describes the energy used when a liquid turns into a gas or a gas condenses into a liquid. There is also the latent heat of sublimation, which occurs when a solid turns directly into a gas. Each type represents a different amount of energy required to rearrange the particles of the substance.

Heat of Vaporization (Benzene+Acetone+Methanol+Water)
Heat of Vaporization (Benzene+Acetone+Methanol+Water)

Our understanding of this phenomenon grew through several key historical discoveries. In 1748, William Cullen reported that diethyl ether could boil by lowering its pressure, even without adding heat.

William Cullen (cropped)
William Cullen (cropped)

In 1758, Benjamin Franklin and John Hadley observed that evaporating ether could actually lower the temperature of a thermometer. However, the most significant breakthrough came from Joseph Black around 1762.

Black Joseph (cropped)
Black Joseph (cropped)

Black was a Scottish chemist working on calorimetry, partly to help Scotch whisky producers optimize their distilling processes. He realized that melting required much more heat than just raising the temperature of the substance. He proved that a large amount of heat was absorbed during melting without a corresponding rise in temperature.

Joseph Black used precise measurements to quantify these hidden energies. In one experiment, he heated equal masses of ice and water to 40 degrees Fahrenheit. The water only required 7 degrees of sensible heat to reach this temperature. The ice, however, required 147 degrees of heat in total. Since the ice temperature only rose by 8 degrees, Black calculated that 139 degrees of heat were absorbed as latent heat.

Black Joseph (cropped)
Black Joseph (cropped)

He also discovered that vaporization requires much more energy than fusion. He found that 830 degrees of heat were needed to vaporize a mass of water. Later, James Prescott Joule characterized latent energy as a form of potential energy related to particle interaction.

In modern science, we use the term specific latent heat to describe this property. Specific latent heat (L) is the amount of heat (Q) required to change the phase of a unit of mass (m). This is expressed by the formula Q = mL. Because it is an intensive property, the value does not depend on the size of the sample. For example, the specific latent heat of fusion for water is 334 kJ/kg. The specific latent heat of vaporization for water is much higher at 2260 kJ/kg. This high value explains why steam is a very effective and hazardous heating medium compared to boiling water.

Latent heat plays a vital role in the Earth's systems, particularly in meteorology. Latent heat flux is the movement of energy from the Earth's surface to the atmosphere. This occurs through the evaporation of water from oceans or through transpiration from plants. When this water vapor rises into the troposphere and condenses into clouds, it releases latent heat. This process is a major component of the Earth's surface energy budget. It helps drive weather patterns and regulates the temperature of the atmosphere and oceans.

Heat of Vaporization (Benzene+Acetone+Methanol+Water)
Heat of Vaporization (Benzene+Acetone+Methanol+Water)
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File:Heat of Vaporization (Benzene+Acetone+Methanol+Water).png
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