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Kaolinite

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Kaolinite is a fundamental clay mineral with the chemical formula Al2Si2O5(OH)4. It is a layered silicate mineral used extensively in global industries. This soft, earthy mineral is typically white in color. It is produced through the chemical weathering of aluminum silicate minerals, such as feldspar. Because of its specific chemical makeup, it has a low cation-exchange capacity, which ranges from 1 to 15 meq/100 g. It also possesses a low shrink–swell capacity, meaning it does not expand significantly when wet.

Beevers crystal structure model of Kaolinite
Beevers crystal structure model of Kaolinite

The internal structure of kaolinite is categorized as a 1:1 or TO clay mineral. This means its crystals consist of stacked layers, where each layer contains two distinct parts. The first part is a tetrahedral (T) sheet made of silicon and oxygen ions. In this sheet, each silicon ion is surrounded by four oxygen ions, forming a tetrahedron. The second part is an octahedral (O) sheet made of oxygen, aluminum, and hydroxyl ions. In this sheet, each aluminum ion is surrounded by six oxygen or hydroxyl ions arranged as an octahedron.

Beevers crystal structure model of Kaolinite
Beevers crystal structure model of Kaolinite

These T and O sheets are strongly bonded together by shared oxygen atoms. However, the way the individual layers connect to one another is different. The layers are held together by hydrogen bonds. These bonds occur between the oxygen on the outer face of one T sheet and the hydroxyl on the outer face of the next O sheet. This tight hydrogen bonding prevents water molecules from infiltrating between the layers. This structural characteristic is the reason why kaolinite is non-swelling. Additionally, because the layers have no net electrical charge, there are no large cations like calcium or sodium between them.

When kaolinite is moistened, its tiny platelike crystals acquire a layer of water molecules. This causes the crystals to adhere to each other, providing the clay with cohesiveness. The bonds are weak enough to allow the plates to slip when the clay is being molded. This makes the material plastic and easy to shape. When the clay dries, most water is removed and the plates hydrogen bond directly to each other. This results in a material that is rigid but remains fragile. If the clay is moistened again, it becomes plastic once more.

China Clay Silos near Par - geograph.org.uk - 30198
China Clay Silos near Par - geograph.org.uk - 30198

The history of the name "kaolin" is tied to the manufacture of porcelain. In 1712, François Xavier d'Entrecolles wrote French reports regarding Jingdezhen porcelain. He transcribed a Chinese term that was later romanized as kaolin. This name originated from the village of Gaoling, which means "High Ridge," located near Ehu in Fuliang County. During the Qing dynasty, this area was the primary source of kaolin for Jingdezhen. Later, the mineralogical suffix "-ite" was added to the name. This allowed the term to describe nearly identical minerals found in other geographic locations.

Kaznějov - kaolin quarry
Kaznějov - kaolin quarry

Kaolinite undergoes several phase transformations when it is treated with heat in air. This process is known as calcination. When heated above 400 °C, hydroxyl ions are lost from the crystal structure as water. This change is irreversible, and the material can no longer be plasticized by water. At temperatures between 550 and 600 °C, the mineral produces a disordered phase called metakaolin. If heating continues to between 925 and 950 °C, metakaolin converts into an aluminum-silicon spinel. Finally, at 1400 °C, a "needle" form of mullite appears. This final stage offers significant increases in heat resistance and structural strength.

Buell Dryer
Buell Dryer

Kaolinite is found globally and is mined in many countries, including Brazil, China, and Australia. In the United States, major deposits exist in central Georgia along the Atlantic Seaboard fall line. This region is known as the "white gold" belt, and the town of Sandersville is called the "Kaolin Capital of the World." In 2021, global production of kaolin was estimated at 45 million tonnes. This production had a total market value of US $4.24 billion.

Kaznějov - kaolin quarry
Kaznějov - kaolin quarry

The presence of kaolinite in soil can tell scientists about the history of the Earth's climate. It is abundant in soils formed from the weathering of rocks in hot, moist climates, such as tropical rainforests. In cooler or drier climates, the proportion of kaolinite decreases. It is often replaced by other minerals like illite or smectite. By studying these mineral proportions in ancient, buried soils, researchers can infer how climates have changed over geological time.

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🖼️ Images & Media (4)
File:Beevers crystal structure model of Kaolinite.jpg
Beevers crystal structure model of Kaolinite.jpg
File:Kaznějov - kaolin quarry.jpg
Kaznějov - kaolin quarry.jpg
File:China Clay Silos near Par - geograph.org.uk - 30198.jpg
China Clay Silos near Par -...
File:Buell Dryer.jpg
Buell Dryer.jpg
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