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Hydrogen halide

physical science Maturity 11-13 Next article →

Hydrogen halides are a group of inorganic, diatomic compounds. A diatomic molecule is made of exactly two atoms. In these specific molecules, one atom is always hydrogen. The other atom is a halogen, which is a group of elements. The chemical formula for these compounds is HX. Here, H stands for hydrogen and X represents a halogen. The halogens involved are fluorine, chlorine, bromine, iodine, astatine, and tennessine.

Hydrogen-fluoride-2D-dimensions
Hydrogen-fluoride-2D-dimensions

These compounds are very important in chemistry. They act as Arrhenius acids when they are dissolved in water. This means they can release ions to change the chemistry of a liquid.

When these gases meet water, a specific process occurs. The dissolution of hydrogen halides in water is highly exothermic. This means the reaction releases a significant amount of heat. Once dissolved, the molecules ionize in the aqueous solution. This process yields hydronium ions, which are written as H3O+. This ionization is what makes them behave as strong acids. Because of this, chemists often use different names for the gas and the liquid. For example, hydrogen chloride is the gas. Once it reacts with water, it becomes hydrochloric acid.

Hydrogen-chloride-3D-vdW
Hydrogen-chloride-3D-vdW

There are several distinct types of hydrogen halides based on their halogen. Hydrogen fluoride (HF) is the first in the series. It is unique because it can form hydrogen bonds between its molecules. This special connection gives it the highest melting and boiling points in the group. The next is hydrogen chloride (HCl), followed by hydrogen bromide (HBr). Then comes hydrogen iodide (HI), which is the least stable. Finally, there are hydrogen astatide (HAt) and hydrogen tennesside (HTs).

Hydrogen-bromide-2D-dimensions
Hydrogen-bromide-2D-dimensions

Each of these follows a pattern of increasing size and different chemical strengths.

Scientists have found these substances in various environments and through different methods. In nature, hydrogen fluoride, chloride, and bromide exist as volcanic gases. Humans produce them through many industrial routes. Hydrogen chloride is often a side product of making chlorocarbons. Hydrogen fluoride is produced as a byproduct during the creation of phosphoric acid. Other methods include reacting halogens like fluorine or chlorine with hydrogen gas. You can also produce them by treating halide salts with sulfuric acid.

Hydrogen-iodide-3D-vdW
Hydrogen-iodide-3D-vdW

Even the unstable hydrogen iodide is made by reacting iodine with hydrazine or hydrogen sulfide.

Physical properties change predictably across the series. Most hydrogen halides are colorless gases at standard temperature and pressure. However, hydrogen fluoride boils at 19 °C. From hydrogen chloride to hydrogen iodide, the boiling point rises steadily. This rise happens because of increasing intermolecular van der Waals forces. These forces are the attractions between molecules. The strength of these forces correlates with the number of electrons in the molecules.

Boiling-points Chalcogen-Halogen
Boiling-points Chalcogen-Halogen

As the atoms get larger and have more electrons, the molecules stick together more effectively.

There are several notable examples of how these chemicals behave in a lab. Concentrated solutions of hydrohalic acids produce visible white fumes. This mist is actually composed of tiny droplets of the aqueous solution. In the field of organic chemistry, these molecules are used for hydrohalogenation. This is a reaction used to prepare halocarbons. For instance, scientists can produce chloroethane by using ethylene and hydrogen chloride. This reaction follows the formula C2H4 + HCl → CH3CH2Cl.

Hydrogen-tennesside-calculated-3D-sf
Hydrogen-tennesside-calculated-3D-sf

Such reactions allow for the building of more complex organic structures.

Hydrogen halides connect to many broader scientific ideas. They serve as a primary example of how acidity works in different solvents. While they are strong acids in water, they are only moderately acidic in non-aqueous solvents like acetonitrile. Their behavior also connects to the study of periodic trends. The way their boiling points and acid strengths change helps chemists understand atomic structure. For example, acid strength generally increases as you move down the halogen group. This helps scientists predict how new or rare elements might behave in chemical reactions.

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