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Hydrogen chalcogenide

physical science Maturity 11-13 Next article →

Hydrogen chalcogenides are a diverse family of chemical compounds. They are formed by combining hydrogen with elements from group 16 of the periodic table. These group 16 elements are known as chalcogens. The chalcogens include oxygen, sulfur, selenium, tellurium, polonium, and livermorium.

Water molecule 3D
Water molecule 3D

This group of chemicals is scientifically important because it includes water. Water is the most common compound on Earth's surface. It covers 70.9% of our planet. While water supports life, most other members of this family behave very differently. Many are highly toxic gases with strong, unpleasant scents. These smells often resemble rotting eggs or decaying vegetables.

Hydrogen-sulfide-3D-vdW
Hydrogen-sulfide-3D-vdW

Most of these compounds follow a specific molecular structure. They are known as dihydrogen chalcogenides with the chemical formula H2X. In this formula, X stands for any chalcogen atom. Because they consist of three atoms, they are called triatomic molecules. These molecules typically adopt a bent geometric shape. This specific shape makes them polar molecules.

Hydrogen-sulfide-2D-dimensions
Hydrogen-sulfide-2D-dimensions

Polarity means the electrical charge is not distributed evenly across the molecule. This property influences how these substances interact with one another and with other chemicals.

Water is a very unique member of this group due to hydrogen bonding. This occurs when hydrogen atoms are attracted to oxygen atoms in neighboring molecules. This strong attraction results in high melting and boiling points. It also leads to high surface tension and high viscosity.

In contrast, other members like hydrogen sulfide lack significant hydrogen bonding. This is why hydrogen sulfide is a gas at standard temperature and pressure. As you move down the group to heavier chalcogens, the properties change again. For example, polonium hydride is a liquid at room temperature. This is due to van der Waals interactions caused by large electron clouds.

Polonium-hydride-3D-vdW
Polonium-hydride-3D-vdW

Scientists use different methods to create these various compounds. Water, hydrogen sulfide, and hydrogen selenide can be made by heating their elements together above 350 °C. However, some compounds are much more difficult to stabilize. Hydrogen telluride is thermally unstable. It decomposes when exposed to moisture, light, or temperatures above 0 °C.

Hydrogen-telluride-2D-dimensions
Hydrogen-telluride-2D-dimensions

Polonium hydride is even more challenging to study. Polonium is a highly radioactive metal. This radioactivity causes self-radiolysis, which means the radiation breaks the compound apart as it forms. Scientists can only obtain trace amounts of polonium hydride by treating polonium-plated magnesium foil with dilute hydrochloric acid.

These compounds also show interesting trends in acidity. When hydrogen selenide, hydrogen telluride, or hydrogen polonide dissolve in water, they form hydrochalcogenic acids. These are acidic solutions where the water turns into a hydronium ion (H3O+). The chalcogen becomes a negative ion (XH−). While these are weaker than hydrohalic acids, they follow a clear pattern. The acid strength increases as the chalcogens become heavier. Therefore, hydrogen telluride is a stronger acid than hydrogen selenide.

Hydrogen-selenide-3D-vdW
Hydrogen-selenide-3D-vdW

There is a related group called dihydrogen dichalcogenides with the formula H2X2. These are generally less stable than the H2X versions. They often decompose into a monochalcogenide and the original chalcogen. The most famous example is hydrogen peroxide (H2O2). It is a pale blue, nearly colorless liquid.

Hydrogen peroxide has a higher density and viscosity than water. It is widely used in households as a disinfectant or for bleaching hair. In its highly concentrated form, it can be quite dangerous. Other members, like hydrogen disulfide, can form longer chains. In the sulfur series, these are called polysulfanes. These sulfur chains can be colorless or yellow depending on their length.

Finally, we can look at how these chemicals relate to other systems. Some researchers study isotopes of water, such as heavy water. Heavy water is created by replacing regular hydrogen with deuterium. Because deuterium is much denser than regular protium, heavy water has many unique properties.

Heavy-water-3D-vdW
Heavy-water-3D-vdW

We also see these elements in biological signaling. For instance, the human body produces small amounts of hydrogen sulfide intentionally. This allows it to function as a signaling molecule within our own systems. Even in chemistry, the hydroxide ion (OH−) from water is a fundamental part of many reactions.

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🖼️ Images & Media (21)
File:H2O 2D labelled.svg
H2O 2D labelled.svg
File:Water molecule 3D.svg
Water molecule 3D.svg
File:Hydrogen-sulfide-2D-dimensions.svg
Hydrogen-sulfide-2D-dimensions.svg
File:Hydrogen-sulfide-3D-vdW.svg
Hydrogen-sulfide-3D-vdW.svg
File:Hydrogen-selenide-2D-dimensions.svg
Hydrogen-selenide-2D-dimensions.svg
File:Hydrogen-selenide-3D-vdW.svg
Hydrogen-selenide-3D-vdW.svg
File:Hydrogen-telluride-2D-dimensions.svg
Hydrogen-telluride-2D-dimensions.svg
File:Hydrogen-telluride-3D-vdW.svg
Hydrogen-telluride-3D-vdW.svg
File:Poloniumwasserstoff.svg
Poloniumwasserstoff.svg
File:Polonium-hydride-3D-vdW.svg
Polonium-hydride-3D-vdW.svg
File:Hydrogen-livermoride-2D-dimensions.svg
Hydrogen-livermoride-2D-dimensions.svg
File:Livermorium-hydride-3D-balls.png
Livermorium-hydride-3D-balls.png

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