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Hydrogen chalcogenide

physical science Maturity 11-13 Next article →

Hydrogen chalcogenides are a special group of chemical compounds. They are made by mixing hydrogen with elements from a group called chalcogens. This group includes oxygen, sulfur, selenium, tellurium, polonium, and livermorium.

Water molecule 3D
Water molecule 3D

The most famous member of this family is water. Water is essential for life on Earth. It covers 70.9% of our planet's surface. Most other compounds in this group are very different from water. Many are toxic gases that have strong, unpleasant smells. They often smell like rotting eggs or old vegetables.

Hydrogen-sulfide-3D-vdW
Hydrogen-sulfide-3D-vdW

These molecules have a specific way they are built. Most follow a formula called H2X. This means they are triatomic, or made of three atoms. They usually take on a bent shape. This shape makes them polar molecules.

Hydrogen-sulfide-2D-dimensions
Hydrogen-sulfide-2D-dimensions

In water, the oxygen atom and two hydrogen atoms stay connected through hydrogen bonding. This special bond gives water high melting and boiling points. It also helps water have high surface tension. Other members like hydrogen sulfide do not have this strong bonding. Because of this, they are often gases at room temperature.

Mp and bp of H2E (E=O,S,Se,Te,Po) Celsius vs atomic number
Mp and bp of H2E (E=O,S,Se,Te,Po) Celsius vs atomic number

Scientists have learned how to make these compounds in different ways. Water, hydrogen sulfide, and hydrogen selenide can be made by heating the elements together above 350 °C.

Hydrogen-selenide-3D-vdW
Hydrogen-selenide-3D-vdW

However, some are much harder to create. Hydrogen telluride is very unstable. It will break down if it touches moisture, light, or heat above 0 °C. Polonium hydride is also very difficult to work with. It is unstable because polonium is highly radioactive. Scientists can only get tiny amounts of it by treating magnesium foil with acid.

Polonium-hydride-3D-vdW
Polonium-hydride-3D-vdW

There are many specific facts about each compound in this series. Hydrogen sulfide is a volcanic gas and a product of decomposition. It is even produced by the human body as a signaling molecule.

Hydrogen-sulfide-2D-dimensions
Hydrogen-sulfide-2D-dimensions

Hydrogen selenide and hydrogen telluride can dissolve in water to form acids. These are called hydrochalcogenic acids. As the chalcogen gets heavier, the acid becomes stronger. For example, hydrogen telluride is a stronger acid than hydrogen selenide.

Hydrogen-telluride-2D-dimensions
Hydrogen-telluride-2D-dimensions

Even the heavy polonium hydride has unique properties because polonium is a metal.

Poloniumwasserstoff
Poloniumwasserstoff

Some of these compounds are very useful in our daily lives. Hydrogen peroxide is a member of a related group called dihydrogen chalcogenides. It is a pale blue, nearly colorless liquid.

You might use it at home as a disinfectant or to bleach hair. There are also larger chains of sulfur atoms called polysulfanes. These can be colorless or yellow depending on their size.

Finally, you may have heard of heavy water. This is made by replacing the regular hydrogen in water with an isotope called deuterium. It is much denser than normal water.

Heavy-water-3D-vdW
Heavy-water-3D-vdW
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🖼️ Images & Media (21)
File:H2O 2D labelled.svg
H2O 2D labelled.svg
File:Water molecule 3D.svg
Water molecule 3D.svg
File:Hydrogen-sulfide-2D-dimensions.svg
Hydrogen-sulfide-2D-dimensions.svg
File:Hydrogen-sulfide-3D-vdW.svg
Hydrogen-sulfide-3D-vdW.svg
File:Hydrogen-selenide-2D-dimensions.svg
Hydrogen-selenide-2D-dimensions.svg
File:Hydrogen-selenide-3D-vdW.svg
Hydrogen-selenide-3D-vdW.svg
File:Hydrogen-telluride-2D-dimensions.svg
Hydrogen-telluride-2D-dimensions.svg
File:Hydrogen-telluride-3D-vdW.svg
Hydrogen-telluride-3D-vdW.svg
File:Poloniumwasserstoff.svg
Poloniumwasserstoff.svg
File:Polonium-hydride-3D-vdW.svg
Polonium-hydride-3D-vdW.svg
File:Hydrogen-livermoride-2D-dimensions.svg
Hydrogen-livermoride-2D-dimensions.svg
File:Livermorium-hydride-3D-balls.png
Livermorium-hydride-3D-balls.png

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