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Halogen

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The halogens are a group of six chemically related elements found in group 17 of the periodic table.

Halogens
Halogens

This group includes fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and two radioactive elements, astatine (At) and tennessine (Ts). The name "halogen" comes from Greek words meaning "salt maker" or "salt producer." This name describes how these elements react with metals to create a wide variety of salts.

Examples of these salts include sodium chloride, which is common table salt, and calcium fluoride. The halogens are unique because they are the only periodic table group containing elements in three different states of matter at standard temperature and pressure. This means some are gases, some are liquids, and some are solids.

Chemical reactivity is the defining characteristic of the halogens. Each halogen atom has seven valence electrons in its outermost energy level. To reach a stable state, they follow the octet rule by attempting to gain one more electron. This drive to acquire an electron makes them highly electronegative and extremely reactive.

Difluorine-2D-dimensions
Difluorine-2D-dimensions

Fluorine is the most reactive element in the entire periodic table. It is even more electronegative than oxygen. Its reactivity is so intense that it can attack materials like glass if small amounts of water are present. In such cases, it can react with the glass to form silicon tetrafluoride. Because of this, scientists must store fluorine in special containers made of metals like copper or steel, or use substances like Teflon.

As you move down the group from fluorine to iodine, the physical properties change in a predictable pattern. The elements become less reactive and their melting points increase. This happens because the atoms get larger, which results in stronger London dispersion forces.

Pressure halogens
Pressure halogens

These forces are caused by having more electrons. While the lighter halogens like fluorine and chlorine are elemental gases, the heavier ones like bromine and iodine have much higher melting points. The middle halogens, specifically chlorine, bromine, and iodine, are frequently used as disinfectants to kill germs. Additionally, organobromides are a major class of chemicals used as flame retardants.

When halogens bond with hydrogen, they create a specific type of compound called a hydrogen halide.

Dibromine-2D-dimensions
Dibromine-2D-dimensions

These include hydrogen fluoride (HF), hydrogen chloride (HCl), hydrogen bromide (HBr), hydrogen iodide (HI), and hydrogen astatide (HAt). When these compounds are mixed with water, they form acids. Most of these, such as hydrochloric and hydrobromic acid, are considered strong acids. However, hydrofluoric acid is classified as a weak acid. These acids are all irritants, and some are highly dangerous. For instance, breathing in more than fifty parts per million of hydrogen chloride gas can be fatal to humans. Similarly, breathing more than thirty parts per million of hydrogen bromide can be lethal.

The history of discovering these elements is a long journey of scientific progress. The mineral fluorspar was known as early as 1529, though chemists could not isolate fluorine for centuries. In 1869, George Gore used electricity to produce fluorine, but he could not prove it. It was not until 1886 that Henri Moissan successfully isolated fluorine through electrolysis. Chlorine was identified later when Carl Wilhelm Scheele heated hydrochloric acid with manganese dioxide in 1774.

Dichlorine-2D-dimensions
Dichlorine-2D-dimensions

Scheele originally called it "dephlogisticated muriatic acid." It was not until 1807 that Humphry Davy proved chlorine was a distinct element.

Other elements in the group were found through diverse chemical processes. Antoine Jérôme Balard discovered bromine in the 1820s by passing chlorine gas through brine.

Iodine-3D-vdW
Iodine-3D-vdW

Bernard Courtois discovered iodine in 1811 while working with seaweed ash. He noticed purple fumes and black crystals during his process. Joseph Gay-Lussac later proved that iodine was a new element. The discovery of astatine was much more difficult, with several mistaken claims in the 1930s. It was finally produced in 1940 by Dale R. Corson, K.R. Mackenzie, and Emilio G. Segrè by bombarding bismuth with alpha particles. The final member, tennessine, was synthesized in 2010 by a large international team of scientists.

Understanding halogens connects to many different areas of science and industry. Their ability to form incredibly strong bonds, especially with carbon, led to the creation of Teflon.

Fluorine-3D-vdW
Fluorine-3D-vdW

Teflon is an organofluorine compound that is extremely resistant to heat and chemical damage. This makes it useful for many high-tech applications. The names of the elements themselves also provide a connection to their physical appearances. For example, the name "chlorine" comes from the Greek word for greenish-yellow, and "iodine" comes from the Greek word for violet. These elements continue to be vital to our understanding of how atoms interact to build the world around us.

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🖼️ Images & Media (10)
File:Difluorine-2D-dimensions.png
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File:Dichlorine-2D-dimensions.png
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File:Chlorine-3D-vdW.png
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File:Dibromine-2D-dimensions.png
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File:Bromine-3D-vdW.png
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File:Diiodine-2D-dimensions.png
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File:Iodine-3D-vdW.png
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File:Pressure halogens.png
Pressure halogens.png
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