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Halide

physical science Maturity 11-13 Next article →

A halide is a special type of chemical compound. It is made of two different parts. One part is always a halogen atom. The other part is an element that is less electronegative. This means the second part is more electropositive.

Atomic & ionic radii halides
Atomic & ionic radii halides

When these parts join, they create a halide. You can find many halides in the form of salts. This connection is why the word 'halite' is used for certain minerals. Common types include fluoride, chloride, bromide, iodide, astatide, or tennesside.

Atomic & ionic radii halides
Atomic & ionic radii halides

Halides can work in a few different ways. Sometimes they form ionic halide salts. In these salts, a halide ion has a negative charge. Many of these ions are colorless. Other halides form covalent bonds instead. For example, TiF4 and TiCl4 are both colorless. However, TiBr4 is orange and TiI4 is brown.

Atomic & ionic radii halides
Atomic & ionic radii halides

Some of these can be distilled easily. This happens because they are molecular. The one exception is TiF4. It has a polymeric structure and a melting point of 284 °C.

Atomic & ionic radii halides
Atomic & ionic radii halides

Chemistry tells us how these compounds react. Halides cannot be reduced in a normal lab. But they can all be oxidized. This turns them back into parent halogens. These halogens are diatomic, which means they come in pairs. For iodide, scientists can see and isolate middle steps. One well-known example is triiodide. There are also many polyiodides.

Atomic & ionic radii halides
Atomic & ionic radii halides

Halides also act as conjugate bases. They come from hydrogen halides, which are gases. In water, these make hydrohalic acids.

Atomic & ionic radii halides
Atomic & ionic radii halides

Some halides react in very specific ways. Salts like NaCl, NaBr, and NaI dissolve well in water. They make clear, colorless solutions. If you add silver nitrate, a reaction happens. This creates a solid called a precipitate.

Atomic & ionic radii halides
Atomic & ionic radii halides

A chloride will make a white precipitate. A bromide will make a pale yellow one. An iodide will make a yellow precipitate.

Atomic & ionic radii halides
Atomic & ionic radii halides

Alkyl halides also react with silver, but they do it more slowly. This is known as the Beilstein test.

Atomic & ionic radii halides
Atomic & ionic radii halides

We use halides in many parts of life. Metal halide lamps are used for street lights. They use less energy than mercury-vapor lamps. They also show colors much better than sodium lamps. These lamps help in greenhouses or rainy places.

Atomic & ionic radii halides
Atomic & ionic radii halides

Silver halides are used in photographic film. When light hits the film, the halides turn into metallic silver. This creates the image.

Atomic & ionic radii halides
Atomic & ionic radii halides

Halides are also used in soldering flux. Chemists also use them to build organic compounds.

Atomic & ionic radii halides
Atomic & ionic radii halides
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