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Ground state

physical science Maturity 5-7 Next article →

In the world of quantum mechanics, every system has different levels of energy. The ground state is the most important level of all. It is defined as the stationary state of the lowest possible energy. This state is also known as the vacuum in quantum field theory. The specific energy found at this lowest level is called the zero-point energy.

Energy levels
Energy levels

Understanding the ground state helps scientists understand how matter behaves at its most basic level. Any state with energy higher than this base level is called an excited state.

Systems move between these levels based on energy changes. When a system gains energy, it moves from the ground state to an excited state. Conversely, systems naturally seek the lowest energy state to remain stable. A key connection exists between energy and temperature. The third law of thermodynamics states that a system at absolute zero temperature exists in its ground state. At this extreme temperature, the system's entropy, or disorder, is determined by how many ground states are available.

Energy levels
Energy levels

Sometimes, a system can have more than one ground state. This phenomenon is called degeneracy. Degeneracy occurs when a unitary operator acts on a ground state and commutes with the system's Hamiltonian. If a system has many different ground states, it is said to have degenerate ground states. However, some systems are much simpler. A perfect crystal lattice is an example of a system with a unique ground state. Because it has only one ground state, it has zero entropy at absolute zero temperature.

Mathematics can prove specific rules about these states. In one dimension, the ground state of the Schrödinger equation has no nodes. A node is a point where a wave function reaches zero. Scientists use a proof by contradiction to show this. If a state had a node, its average kinetic energy could be lowered by removing that node. By deforming the wave function to remove the node, the energy decreases. Since the ground state must be the lowest energy state, it cannot have nodes.

particle in a box wavefunctions 2
particle in a box wavefunctions 2

This lack of nodes has important implications for how particles are positioned. Because the ground state has no nodes, it is spatially non-degenerate. This means there are no two stationary quantum states with the same energy and spin that differ only in position. However, ground states can still be degenerate if they have different spin states. For example, two states might have the same position-space wave function but different spins. This allows for a ground state to be degenerate without breaking the rule about nodes.

particle in a box wavefunctions 2
particle in a box wavefunctions 2

We can see these principles in specific scientific examples. Consider a particle trapped in a one-dimensional box. The wave function for its ground state is a half-period sine wave. This wave reaches zero at the two edges of the box. The energy of this particle is calculated using the mass, the Planck constant, and the width of the box.

particle in a box wavefunctions 2
particle in a box wavefunctions 2

Another example is the hydrogen atom. The electron in a hydrogen atom has a ground state called the 1s atomic orbital. This is a spherically symmetric distribution centered on the nucleus. The electron is most likely to be found at a distance known as the Bohr radius. For hydrogen, the electron's energy in this state is -13.6 eV relative to the ionization threshold.

particle in a box wavefunctions 2
particle in a box wavefunctions 2

These tiny quantum states even allow us to measure time with incredible precision. Since 1997, the official definition of one second has been tied to the caesium-133 atom. Scientists measure the radiation from the transition between two hyperfine levels of the ground state. This measurement is taken while the caesium-133 atom is at rest at a temperature of 0 K. This connection between the smallest energy states and our measurement of time shows how fundamental the ground state is to our understanding of the universe.

Energy levels
Energy levels
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