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Ground state

physical science Maturity 5-7 Next article →

Everything in the universe has different levels of energy. The lowest possible energy level is called the ground state.

Energy levels
Energy levels

In this state, a system is at its most calm and stable. Scientists also call this a stationary state. The energy at this very bottom level is known as zero-point energy. Any level higher than this is called an excited state.

particle in a box wavefunctions 2
particle in a box wavefunctions 2

When a system gains energy, it jumps up to these higher levels.

How does a system stay in the ground state? One way to look at it is through temperature. The third law of thermodynamics tells us about this. It says a system at absolute zero temperature stays in its ground state. At this temperature, the system has the least amount of disorder, or entropy. Some things, like a perfect crystal lattice, have only one unique ground state. This means they have zero entropy at absolute zero. Other systems might have more than one ground state. This special situation is called degeneracy.

Energy levels
Energy levels

Scientists have studied how these states work using math. In one dimension, the ground state has a special rule. It cannot have any nodes. A node is a place where a wave function reaches zero. If a wave had a node, it would have more energy. You could lower the energy by smoothing out the wave. This would remove the node and create a lower energy state. Therefore, the true ground state must be smooth and have no nodes.

particle in a box wavefunctions 2
particle in a box wavefunctions 2

We can see these rules in real atoms and particles. For example, a particle in a tiny box has a ground state. Its wave function looks like a half-period sine wave. The energy for this particle depends on its mass and the box width. In a hydrogen atom, the electron has a ground state too. Its wave function is a shape centered on the nucleus. The electron is most likely to be at the Bohr radius. For hydrogen, the electron has an energy of -13.6 eV in this state.

particle in a box wavefunctions 2
particle in a box wavefunctions 2

These tiny energy levels even help us keep track of time. Since 1997, the definition of one second has been very specific. It is based on the caesium-133 atom. Scientists look at the transition between two hyperfine levels of its ground state. This happens at a temperature of 0 K. By measuring these tiny shifts, we can define time very accurately. It is amazing how the smallest states of matter guide our whole world.

Energy levels
Energy levels
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