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Degenerate energy levels

physical science Maturity 5-7 Next article →

In the field of quantum mechanics, energy levels define the specific amounts of energy a system can possess. Usually, a single energy value corresponds to just one unique state. However, a phenomenon called degeneracy occurs when two or more different measurable states share the exact same energy value.

The number of distinct states associated with a specific energy level is known as the degree of degeneracy. When degeneracy is present, measuring the energy alone is insufficient to identify the exact state of the system. Scientists must use additional quantum numbers to distinguish between these different states.

To understand this mathematically, we treat the possible states of a quantum system as abstract vectors. These vectors exist within a complex Hilbert space. Physical observables are represented by linear Hermitian operators that act upon these vectors. When an operator acts on a vector and results in the same vector multiplied by a scalar, that scalar is called an eigenvalue. The vector itself is known as the eigenvector. If an eigenvalue corresponds to two or more linearly independent eigenvectors, that eigenvalue is considered degenerate. The set of all these eigenvectors forms a subspace called an eigenspace. The dimension of this eigenspace tells us the degree of degeneracy.

Degeneracy behaves differently depending on the number of dimensions in the system. In a one-dimensional system, such as a particle moving along a single line, degeneracy is extremely limited. For a particle in a one-dimensional potential, the degree of degeneracy never exceeds two. In fact, it has been proven that there are no degenerate bound states for normalizable wave functions in one dimension. This is because the time-independent Schrödinger equation acts as an ordinary differential equation in this setting. This mathematical constraint prevents the complex patterns seen in higher dimensions.

As we move into two-dimensional systems, the complexity increases significantly. Scientists study two-dimensional quantum systems to understand more complex three-dimensional matter. Real-world examples include monoatomic layers on the surface of solids. Experimental examples include two-dimensional electron systems like MOSFETs or superlattices of Helium, Neon, Argon, and Xenon. A common model used to study these systems is the "particle in a box." In a rectangular two-dimensional box with impenetrable walls, energy depends on two quantum numbers. If the box is a perfect square, the dimensions are equal. In this square setup, certain pairs of states become degenerate because the energy values remain the same even if the quantum numbers are swapped.

Lifting of degeneracy (energy level diagram)
Lifting of degeneracy (energy level diagram)

In a three-dimensional cubic box, the energy levels depend on three different quantum numbers. Because these three numbers can be interchanged without changing the energy, every energy level has a degeneracy of at least three, provided the numbers are not all equal. This shows how the geometry of a space directly influences its quantum properties. For example, if the three quantum numbers are different, you can swap their positions in several ways to get the same energy. This creates a larger eigenspace and a higher degree of degeneracy. The more ways a system can be rearranged without changing its energy, the higher the degeneracy will be.

One way to manage this complexity is by finding a complete set of commuting observables. If an energy level is degenerate, simply knowing the energy does not provide a unique basis of eigenvectors. However, if we find another observable that commutes with the Hamiltonian, we can use it to label the states. Two operators commute if the order in which they are applied does not change the result. By choosing these additional commuting observables, scientists can construct an orthonormal basis. This allows them to assign unique labels to each state, even when they share the same energy level. This process is vital for characterizing the exact state of a quantum system.

The physical origin of degeneracy is often found in the symmetry of the system. Symmetry means the system remains unchanged under certain transformations, such as rotation or reflection. For example, the parity operator looks at whether a state is even or odd by changing the position vector to its negative. If a potential is even, the Hamiltonian is also an even operator. Studying these symmetries allows scientists to predict energy levels and degeneracy without solving the full Schrödinger equation. This connection between symmetry and degeneracy is a fundamental principle that helps simplify the study of the physical world.

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File:Degenerate energy levels.svg
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File:Lifting of degeneracy (energy level diagram).png
Lifting of degeneracy (energy level diagram).png
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