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Flame test

physical science Maturity 9-11 Next article →

A flame test is a quick way to find certain elements in a sample.

Scientists use this method to see which metals are present. While the technique is older and less reliable than modern tools, it is still very useful. It was once a main part of qualitative inorganic analysis. Today, it is often used in schools to teach students about metals.

This test is closely related to pyrotechnics and the study of light called spectroscopy.

To perform the test, you introduce a sample into a hot, non-luminous flame.

A Student Conducting the Chemical Experiment using Crucible
A Student Conducting the Chemical Experiment using Crucible

You can use many different supports, like platinum wires or wooden splints. Sometimes, a sample is made into a paste using hydrochloric acid. This helps because metal halides are volatile and give better results. The color of the flame can change based on the temperature or the oxygen used.

Electron excitation
Electron excitation

You might even use cobalt blue glass to view the flame. This glass filters out the bright yellow light from sodium. This helps you see other metal colors more clearly.

The science behind the color is called electron excitation.

Electron excitation
Electron excitation

When the heat hits the atoms, it gives energy to the electrons. These electrons move to a higher energy state. When they relax back to their normal ground state, they release energy as a photon. This photon is a tiny particle of light. Each element has its own unique energy levels. Because of this, every element produces a specific color of light. This is the same principle used in flame emission spectroscopy.

History shows how these tests became more accurate over time. Robert Bunsen invented the Bunsen burner in 1855.

BaCl Flame colour
BaCl Flame colour

His burner created a non-luminous flame that did not hide the test colors. Bunsen and Gustav Kirchhoff later used a prism to look at these colors. In 1860, they saw unexpected sky-blue and dark red colors in the light. This led them to discover two new alkali metals. They found that caesium produces sky blue and rubidium produces dark red.

Die Flammenfärbung des Rubidium
Die Flammenfärbung des Rubidium

Many different elements create beautiful colors in a flame.

Flametest--Cu.swn
Flametest--Cu.swn

For example, copper creates a blue-green flame. Lithium produces a carmine red color.

FlammenfärbungLi
FlammenfärbungLi

Barium makes an apple green flame.

BaCl Flame colour
BaCl Flame colour

Strontium can look crimson or scarlet red.

FlammenfärbungSr
FlammenfärbungSr

Some elements, like gold or silver, do not show a specific color. Instead, they might just produce sparks. Knowing these colors helps us identify the hidden building blocks of the world.

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🖼️ Images & Media (26)
File:Flame test.jpg
Flame test.jpg
File:A Student Conducting the Chemical Experiment using Crucible.jpg
A Student Conducting the Chemical...
Flame Tests of Metal Ions, With Labels.webm
File:Electron_excitation.png
Electron_excitation.png
File:Coloured flames of methanol solutions of metal salts and compounds.jpg
Coloured flames of methanol solutions of...
File:FlammenfärbungAs.jpg
FlammenfärbungAs.jpg
File:FlammenfärbungB.png
FlammenfärbungB.png
File:BaCl Flame colour.jpg
BaCl Flame colour.jpg
File:FlammenfärbungCa.png
FlammenfärbungCa.png
File:CobaltFlameTestOxyHydrogen.png
CobaltFlameTestOxyHydrogen.png
File:ChromiumFlameTestOxyHydrogen.png
ChromiumFlameTestOxyHydrogen.png
File:CaesiumFlameTestOxyHydrogen.png
CaesiumFlameTestOxyHydrogen.png

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