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Desiccant

physical science Maturity 5-7 Next article →

A desiccant is a hygroscopic substance used to create or maintain dryness. This process of removing moisture is called desiccation. Desiccants are the opposite of humectants, which are substances that hold moisture.

Silica gel bag open with beads
Silica gel bag open with beads

These materials are essential for protecting many different products. They can be found in food to keep it crisp. They are also used in industry to control water in gas streams. By pulling water away, they prevent damage and decay.

Desiccants work through several different scientific mechanisms. Some are solids that absorb water into their structure. Other specialized types work through the chemical bonding of water molecules. For example, some substances react chemically to grab water from their surroundings. Efficiency is measured by the ratio of water stored relative to the mass of the desiccant. Another way to measure performance is the residual relative humidity of the air. When drying gases, scientists look at the dew point of the dried product.

Molecular Sieve5
Molecular Sieve5

This tells them exactly how much water remains in the gas.

There are many different types of desiccants used today. Silica gel is the most common variety. It is a white, nontoxic, and water-insoluble solid. It is also chemically inert, meaning it does not react with other substances. Other common types include activated charcoal and calcium chloride. There are also molecular sieves, which are typically made of zeolites. Some desiccants are categorized as types I through V. These types are based on the shape of the moisture sorption isotherm.

Indicating-silica-gel
Indicating-silica-gel

Some desiccants are liquids, such as diethylene glycol or alcohols.

Some desiccants are very reactive and require specialized handling. For instance, phosphorus pentoxide (P5O5) is a reactive solid with a dew point of -98°C. Potassium hydroxide (KOH) is a caustic solid with a dew point between -60 and -73°C. Sulfuric acid (H2SO4) is a strong acid used for drying. In contrast, diethylene glycol is an unreactive liquid with a dew point of -15°C. Because some of these are caustic or strong acids, they must be used with great care.

Toluene with sodium-benzophenone
Toluene with sodium-benzophenone

Using the right material depends on the specific job required.

In the petrochemical industry, desiccants play a massive role. Natural gas must be anhydrous, or nearly dry, for transport and processing. If water is present, it can form solid methane hydrates. These hydrates can grow inside pipes and cause dangerous blockages. Diethylene glycol is used specifically to absorb water from natural gas to prevent this. Additionally, catalysts used to process petroleum are often deactivated by even tiny amounts of water. Keeping these systems dry is vital for industrial safety and efficiency.

Desiccants are also used in many everyday objects. In insulated windows, zeolite spheroids fill a small spacer tube around the glass. This prevents moisture from condensing between the panes. Zeolites are also used in the "dryer" part of refrigeration systems. They absorb water carried by the refrigerant over time. In shipping, bagged desiccants protect goods in sealed containers from rust and corrosion. They also protect hygroscopic cargo like cocoa, coffee, grains, and nuts. This helps prevent mold and rot caused by humidity.

Scientists also use desiccants in laboratories and medicine. Pharmaceutical companies include small packets in packaging to keep water vapor levels low. In labs, molecular sieves are often used to dry solvents. They are often superior to chemical reagents because they are safe in air and recyclable.

Indicating-silica-gel
Indicating-silica-gel

Some desiccants even include color indicators to show when they are full. Cobalt chloride is one such indicator. It is blue when anhydrous, but turns purple when it bonds with two water molecules. If it gains even more water, it becomes a pink hexaaquacobalt(II) chloride complex. However, cobalt chloride is a potential carcinogen, so its use is carefully managed.

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🖼️ Images & Media (4)
File:Molecular Sieve5.jpg
Molecular Sieve5.jpg
File:Silica gel bag open with beads.jpg
Silica gel bag open with beads.jpg
File:Indicating-silica-gel.png
Indicating-silica-gel.png
File:Toluene with sodium-benzophenone.jpg
Toluene with sodium-benzophenone.jpg
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