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Calcium sulfate

physical science Maturity 5-7 Next article →

Calcium sulfate is an inorganic salt with the chemical formula CaSO4. It is a vital substance found in many different forms throughout the Earth. This salt is important because it can change its structure based on how much water it holds. These different states allow it to be used in everything from building houses to making food.

The way calcium sulfate behaves depends on its level of hydration. Hydration refers to how many water molecules are tucked into its crystal structure. The substance exists in three main levels. First is the dihydrate form, known as the mineral gypsum. Gypsum can appear as colorless or white crystals called selenite or as fibrous masses called satin spar. Second is the hemihydrate state, often called bassanite or plaster of Paris. Third is the anhydrous state, which contains very little to no water. The anhydrous form is known as anhydrite and usually appears as a white crystalline solid.

CaSO4
CaSO4

Scientists study how these forms change through heating and cooling. To create bassanite from gypsum, you must use judicious heating. This process is called dehydration, where water is driven out of the mineral's structure. This requires temperatures between 100 °C and 150 °C. During this process, the heat energy is used to turn the water into vapor. This is an endothermic reaction, meaning it absorbs heat. If you heat it even higher, up to 250 °C, you create a nearly water-free form called γ-anhydrite. If you heat it above 250 °C, you reach the completely anhydrous state called β-anhydrite.

CaSO4
CaSO4

One of the most useful properties of calcium sulfate is its ability to revert to gypsum. When you mix powdered plaster of Paris with water, it undergoes a chemical change. It quickly turns back into the dihydrate form. This reaction is exothermic, which means it releases heat. As it changes, it physically sets into a rigid and strong crystal lattice. This makes it perfect for making molds for metal casting or for creating sticks of blackboard chalk. It can also be used to make a moldable paste for stucco or drywall.

CaSO4
CaSO4

In construction, calcium sulfate plays a critical role in safety. Drywall is often made using these materials. Because the dehydration of gypsum is endothermic, it helps provide fire resistance to buildings. During a fire, the water inside the gypsum turns to steam. This process absorbs heat and keeps the structure behind the drywall relatively cool. This can stop wood from burning or prevent steel from losing its strength. This helps prevent the entire building from collapsing during an emergency.

Calcium sulfate is also widely used in the food and medical industries. In food, it is known as E516 or a firming agent. The FDA permits its use in cheese, cereal flours, bakery products, and even some candies. It is also used as a coagulant to help make tofu. In dentistry, the material is highly valued because it is biocompatible. This means the human body accepts it well without a significant negative response. Dentists use it for bone regeneration and as a graft material.

Drierite
Drierite

Beyond these uses, the substance is important in industrial chemistry. It can be used as a desiccant, which is a substance that soaks up moisture. A common brand is Drierite, which uses cobalt(II) chloride to show when it is working. The powder stays blue when it is dry but turns pink once it has absorbed water.

Drierite
Drierite

Historically, anhydrous calcium sulfate was even used to produce sulfuric acid. By roasting it with shale at 1400 °C, workers could liberate sulfur dioxide gas. Today, the world produces about 127 million tonnes of natural gypsum every year through mining and quarrying.

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