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Anhydrite

earth science Maturity 7-9 Next article →

Anhydrite is a mineral composed of anhydrous calcium sulfate. Its chemical formula is CaSO4. This means it is a calcium sulfate without water. It belongs to the orthorhombic crystal system. This system describes how its internal atoms are arranged. The mineral has three directions of perfect cleavage. This means it breaks easily along three specific flat planes. It is not isomorphous with baryte or celestine. Even though those minerals have similar formulas, their structures are different.

Anhydrite
Anhydrite

Anhydrite undergoes a unique chemical transformation when it meets water. It readily absorbs water to become gypsum. Gypsum has the formula CaSO4·2H2O. This means it contains two molecules of water. This process is reversible. You can turn gypsum back into anhydrite by heating it. This happens under normal atmospheric conditions. In nature, anhydrite forms from aqueous solutions. If the solution has too much sodium or potassium chloride, anhydrite forms at temperatures above 40°C. This is how the mineral forms naturally in salt basins.

Geologists find anhydrite in several distinct environments. It is often found in evaporite deposits alongside gypsum. One famous location is a salt mine near Hall in Tirol. In these deposits, depth is a very important factor. Near the surface, groundwater often turns anhydrite into gypsum. Anhydrite also forms in tidal flat environments. In the Persian Gulf sabkhas, it forms as massive replacement nodules. These nodules often have a netted appearance. Scientists call this specific texture "chicken-wire anhydrite."

Chickenwire Gypsum anhydrite
Chickenwire Gypsum anhydrite

Another common setting is within salt domes. Anhydrite makes up about 1% to 3% of the minerals in these domes. It often remains as a caprock at the top of the salt. This happens when pore waters remove the halite. A typical caprock has a specific order of layers. It starts with salt at the bottom. Above that is a layer of anhydrite. Then comes a layer of gypsum patches. Finally, a layer of calcite sits on top.

History shows us how our understanding of this mineral has changed. A man named A. G. Werner named it in 1804. He chose "anhydrite" because it lacks the water of crystallization found in gypsum. In the past, people used different names. One obsolete name was muriacite. This name was used because people thought it was a chloride. Another old name was karstenite. There are also specific names for different varieties of the mineral. A contorted variety is called tripe-stone. A scaly variety from Italy is called vulpinite.

Anhydrite Kiln by Ophelia Gordon Bell
Anhydrite Kiln by Ophelia Gordon Bell

Anhydrite has physical properties that help scientists identify it. It has a Mohs hardness of 3.5. This means it is relatively soft. Its specific gravity is 2.9. The color is usually white. However, it can also appear greyish, bluish, or purple. The luster changes depending on the surface. On its best cleavage planes, the luster is pearly. On other surfaces, it looks glassy. A semi-transparent light blue-grey variety from Peru is sold as angelite. This variety is quite beautiful.

Understanding anhydrite is important for studying Earth's systems. In oil fields, it can interact with hydrocarbons. At high temperatures, this interaction can cause thermochemical sulfate reduction, or TSR. This process reduces sulfate into hydrogen sulfide. It also causes calcite to precipitate. Anhydrite can even be found in igneous rocks. It was found in the El Teniente pluton in Chile. It was also found in the trachyandesite pumice of the El Chichón volcano in Mexico. Even the movement of water can cause problems. In 2007, drilling in Germany allowed water to hit an anhydrite layer. This caused the ground to swell as the mineral turned into gypsum.

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🖼️ Images & Media (3)
File:Anhydrite.png
Anhydrite.png
File:Chickenwire Gypsum anhydrite.jpg
Chickenwire Gypsum anhydrite.jpg
File:Anhydrite Kiln by Ophelia Gordon Bell.jpg
Anhydrite Kiln by Ophelia Gordon Bell.jpg
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