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Buckminsterfullerene

physical science Maturity 11-13 Next article →

Buckminsterfullerene is a very special type of molecule made of carbon. People often call these tiny structures "buckyballs."

Buckball-electronic-str en
Buckball-electronic-str en

This molecule is famous because of its unique cage-like shape. It is a truncated icosahedron, which is a math term for a specific shape. This shape is made of twenty hexagons and twelve pentagons. Because of this, the molecule looks just like a football.

Football Pallo valmiina-cropped
Football Pallo valmiina-cropped

It is a black solid in its natural state. If you dissolve it in certain liquids, the solution turns a deep purple color.

C60 Fullerene solution
C60 Fullerene solution

How does this tiny cage stay together? The structure is held together by sixty carbon atoms. Each individual atom is bonded to three of its neighbors.

Buckball-electronic-str en
Buckball-electronic-str en

These bonds create a strong, closed shell. The molecule has two different types of bond lengths. The bonds between two hexagons are shorter than the bonds between a hexagon and a pentagon. The average length of a bond is only 0.14 nanometers. The whole molecule is very small, with a diameter of about 1.01 nanometers.

Buckball-electronic-str en
Buckball-electronic-str en

Scientists discovered these molecules in 1985. A team at Rice University led by Harold Kroto, James R. Heath, Sean C. O'Brien, Robert Curl, and Richard Smalley identified the structure. They used a laser to vaporize graphite. This created a hot plasma that was passed through helium gas. This process helped the carbon atoms cool and form clusters. The team saw a strong signal at 720 daltons, which showed sixty carbon atoms were forming. For this great work, Kroto, Curl, and Smalley won the 1996 Nobel Prize in Chemistry.

C60 Fullerene solution
C60 Fullerene solution

There are many interesting facts about where these molecules live. Buckminsterfullerene is the most common type of fullerene found in nature. You can find small amounts of it in soot.

C60-Fulleren-kristallin
C60-Fulleren-kristallin

It even exists out in space! It can be found in planetary nebulae and near certain types of stars. In the interstellar medium, it can even be found in an ionized form. This form helps create special light patterns called diffuse interstellar bands.

UV-Vis C60
UV-Vis C60

This molecule connects to many things we see every day. The name comes from an architect named R. Buckminster Fuller. He was famous for designing geodesic dome structures. These buildings have shapes that look very much like the buckyball.

Football Pallo valmiina-cropped
Football Pallo valmiina-cropped

Even though it is a tiny molecule, it has many different uses. Scientists study how it reacts with things like fluorine or oxygen. Some researchers even found that if you compress it, it can turn into a superhard form of diamond.

Fullerite structure
Fullerite structure
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🖼️ Images & Media (13)
File:Football Pallo valmiina-cropped.jpg
Football Pallo valmiina-cropped.jpg
File:Buckball-electronic-str en.svg
Buckball-electronic-str en.svg
File:Dodecahedron t12 v.png
Dodecahedron t12 v.png
File:Dodecahedron t12 e56.png
Dodecahedron t12 e56.png
File:Dodecahedron t12 e66.png
Dodecahedron t12 e66.png
File:Icosahedron t01 A2.png
Icosahedron t01 A2.png
File:Icosahedron t01 H3.png
Icosahedron t01 H3.png
File:C60 Fullerene solution.jpg
C60 Fullerene solution.jpg
File:UV-Vis C60.jpg
UV-Vis C60.jpg
File:C60-Fulleren-kristallin.JPG
C60-Fulleren-kristallin.JPG
File:Fullerite structure.jpg
Fullerite structure.jpg
File:Addition of O atom into C60 Scheme.png
Addition of O atom into C60 Scheme.png

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