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Arsenic

physical science Maturity 7-9 Next article →

Arsenic is a chemical element with the symbol As and atomic number 33.

Arsenic symbol
Arsenic symbol

It is classified as a metalloid, meaning it possesses properties of both metals and non-metals. As a member of the pnictogen group, it shares chemical characteristics with phosphorus and antimony. This element is famously toxic to most multicellular life forms. However, arsenic is also a vital component in modern technology. It is used in semiconductors and various industrial alloys. Understanding its chemical nature helps us manage its risks and utilize its properties.

Arsenic exists in several different structural forms called allotropes. The most stable and industrially significant form is grey arsenic.

Arsenic nodule
Arsenic nodule

This form has a metallic appearance and a double-layered structure. It consists of many interlocked, ruffled, six-membered rings. Because the bonding between these layers is weak, grey arsenic is brittle. It has a Mohs hardness of 3.5 and a high density of 5.73 g/cm3. Another form is yellow arsenic, which is soft, waxy, and highly volatile.

Mineraly.sk - realgar
Mineraly.sk - realgar

This unstable version is the most toxic allotrope. There is also black arsenic, which is a glassy, brittle material. Black arsenic is a poor electrical conductor and can be formed by cooling vapor at specific temperatures.

Chemical reactions involving arsenic often produce distinct sensory effects. When arsenic is heated in the air, it oxidizes to form arsenic trioxide. This process creates fumes that smell like garlic. This odor can even be detected by striking minerals like arsenopyrite with a hammer. Arsenic can also react with fluorine to create arsenic pentafluoride. In its solid form, arsenic can sublime, which means it turns directly from a solid to a gas without melting. It only melts under specific high-pressure conditions. These chemical behaviors make arsenic highly reactive with various nonmetals.

In the industrial world, arsenic serves several specialized roles. It is a primary component in III-V compound semiconductors, such as gallium arsenide.

Trimethylarsine-2D
Trimethylarsine-2D

These materials are essential for modern electronic devices. Arsenic is also used as an n-type dopant in semiconductors. In metallurgy, it is added to lead to create alloys used in ammunition and car batteries. Historically, arsenic and its compounds like trioxide were used in pesticides, herbicides, and treated wood. However, the use of these chemicals is declining. This decline is due to the growing recognition of their persistent toxicity to the environment.

Humans have been aware of arsenic's poisonous nature since ancient times.

The Arsenic Labyrinth at Botallack Mine - geograph.org.uk - 490315
The Arsenic Labyrinth at Botallack Mine - geograph.org.uk - 490315

While it is dangerous to humans, nature shows us different perspectives. Some species of bacteria can actually use arsenic compounds as respiratory metabolites. This means they use them during their breathing processes. In certain animals, such as rats, hamsters, goats, and chickens, trace amounts may even be an essential part of their diet. However, if the quantity exceeds what the body requires, it results in arsenic poisoning.

Arsenic is a significant environmental concern on a global scale. Contamination of groundwater affects millions of people around the world. The United States Environmental Protection Agency states that all forms of arsenic pose a serious risk to human health. Furthermore, arsenic is classified as a group-A carcinogen, meaning it can cause cancer. In 2001, the United States Agency for Toxic Substances and Disease Registry ranked arsenic as the number one hazardous substance at Superfund sites. This high ranking reflects the extreme danger it poses to ecosystems and human populations.

Arsenic is relatively abundant in the Earth's crust, ranking as the 53rd most common element. It makes up approximately 1.5 parts per million of the crust.

World Arsenic Production 2006
World Arsenic Production 2006

In the oceans, it is the 22nd most abundant element in seawater. Most commercial arsenic is extracted from minerals such as arsenopyrite. In 2015, Peru and China dominated the production of white arsenic, holding nearly 89% of the global market share. As mining moves into deeper, high-impurity ores, the presence of arsenic in copper concentrates has increased. This makes the management of arsenic a central challenge for modern mining and environmental science.

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🖼️ Images & Media (12)
File:SbAs lattice.png
SbAs lattice.png
File:Arsenic nodule.jpg
Arsenic nodule.jpg
File:Trimethylarsine-2D.png
Trimethylarsine-2D.png
File:Native arsenic.jpg
Native arsenic.jpg
File:World Arsenic Production 2006.svg
World Arsenic Production 2006.svg
File:Mineraly.sk - realgar.jpg
Mineraly.sk - realgar.jpg
File:Arsenic symbol.svg
Arsenic symbol.svg
File:The Arsenic Labyrinth at Botallack Mine - geograph.org.uk - 490315.jpg
The Arsenic Labyrinth at Botallack Mine -...
File:A chemist gives a demonstration involving arsenic Wellcome V0011761.jpg
A chemist gives a demonstration involving...
File:Roxarsone.png
Roxarsone.png
File:ArsenobetainePIC.svg
ArsenobetainePIC.svg
File:Improved rice cooking approach to maximise arsenic removal while preserving nutrient elements.jpg
Improved rice cooking approach to...
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