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Selenium

physical science Maturity 11-13 Next article →

Selenium is a chemical element with the symbol Se and atomic number 34. It is a versatile substance that can exist in many different physical forms. These forms are known as allotropes, which are different structural arrangements of the same atoms. Selenium can appear as a brick-red powder, a black vitreous solid, or a grey metallic-looking form.

Selenium trigonal
Selenium trigonal

It is classified as a nonmetal or sometimes a metalloid. This means its properties sit between those of metals and nonmetals. It shows similarities to the elements sulfur and tellurium, as well as arsenic. Because of these unique traits, selenium plays vital roles in both biology and technology.

Understanding how selenium changes requires looking at its molecular structure. When selenium is prepared through chemical reactions, it usually forms an amorphous, brick-red powder. If this substance is melted rapidly, it becomes a black, vitreous solid. This black form is brittle and lustrous. Its structure is quite complex, consisting of polymeric rings that can contain up to 1000 atoms.

Selenium-dioxide-chain-3D-balls
Selenium-dioxide-chain-3D-balls

Temperature plays a major role in how these shapes shift. Black selenium softens at 50 °C. If you continue heating it to 180 °C, it converts into grey selenium. The presence of certain chemicals, like halogens or amines, can actually lower the temperature needed for this change.

Gray selenium is the most stable and dense version of the element. Unlike the other forms, gray selenium is a semiconductor. A semiconductor is a material that can conduct electricity under specific conditions. This makes it highly photoconductive, meaning it responds to light. In this state, the atoms form helical polymeric chains in a hexagonal crystal lattice. The distance between the selenium atoms in these chains averages 237.3 pm.

Selenium trigonal
Selenium trigonal

This specific arrangement allows it to resist oxidation by air and withstand nonoxidizing acids.

The discovery of selenium is a famous story in chemistry. In 1817, scientists Jöns Jacob Berzelius and Johan Gottlieb Gahn were working near Gripsholm, Sweden. They were using pyrite samples from the Falun Mine to produce sulfuric acid. They noticed a red solid precipitate that smelled like horseradish when burned. At first, they thought it was an arsenic compound. However, the smell reminded them of tellurium.

Luna statue
Luna statue

Because tellurium was named after the Earth, Berzelius decided to name this new element after the Moon. He chose the name selenium, which comes from Selene, the Greek goddess of the Moon.

Selenium is found in nature in several different forms, known as isotopes. There are seven naturally occurring isotopes of selenium. The most abundant is 80Se, which makes up 49.6% of all natural selenium.

Polyselenide
Polyselenide

There is also a long-lived primordial radionuclide called 82Se. It has a massive half-life of 8.76×10^19 years. Other isotopes, like 79Se, appear in tiny amounts in uranium ores due to nuclear fission. In a laboratory, scientists can create unstable synthetic isotopes. These range from 64Se to 95Se, with some lasting only a few days.

In the modern world, selenium has many important commercial uses. It is a byproduct of refining metal sulfide ores, where it often substitutes for sulfur. Today, it is used heavily in glassmaking and the production of pigments. Because it is a semiconductor, it was once very important in electronics. While silicon has mostly replaced it in many devices, selenium is still used in certain DC power surge protectors. It is also used in one type of fluorescent quantum dot.

Selenium in sandstone Westwater Canyon Section 23 Mine Grants, New Mexico
Selenium in sandstone Westwater Canyon Section 23 Mine Grants, New Mexico

Some of its compounds, like selenium disulfide, are used in shampoos to treat dandruff.

Biology shows us that selenium is a delicate balance for living things. Many animals and humans require trace amounts of selenium for cellular function. It is a key component in important antioxidant enzymes. These include glutathione peroxidase, thioredoxin reductase, and three different deiodinase enzymes. Because it is so necessary, it is added to infant formula and many multivitamins. However, too much selenium is dangerous. Even small doses of elemental selenium or its salts can be toxic. This toxicity causes a condition called selenosis. Symptoms can include fatigue, hair loss, joint pain, and nail discoloration.

Luna statue
Luna statue
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🖼️ Images & Media (5)
File:Selenium trigonal.jpg
Selenium trigonal.jpg
File:Selenium-dioxide-chain-3D-balls.png
Selenium-dioxide-chain-3D-balls.png
File:Polyselenide.svg
Polyselenide.svg
File:Luna statue.jpg
Luna statue.jpg
File:Selenium in sandstone Westwater Canyon Section 23 Mine Grants, New Mexico.jpg
Selenium in sandstone Westwater Canyon...
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