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Anodizing

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Anodizing is an electrolytic passivation process used to increase the thickness of a metal's natural oxide layer. This process is essential for improving the durability and appearance of many metal parts. By growing a controlled oxide layer on the surface, engineers can increase resistance to corrosion and wear. It also provides better adhesion for glues and paint primers than bare metal.

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Cheap carabiners

Beyond protection, anodizing offers various cosmetic effects. Some thick, porous coatings can absorb dyes to create vibrant colors. Other thin coatings produce colors through a phenomenon called thin film interference.

Anodizing interference coloring
Anodizing interference coloring

The mechanism of anodizing relies on the principles of electrolysis. During the process, the metal part to be treated serves as the anode, which is the positive electrode in an electrolytic cell. A direct current of electricity is passed through an electrolytic solution. This current releases hydrogen at the cathode, the negative electrode, and oxygen at the surface of the metal anode. This oxygen reacts with the metal to create a build-up of metal oxide.

Colored aluminium key blanks
Colored aluminium key blanks

Most industrial processes use an acidic solution, such as sulfuric acid, to perform this task. The acid slowly dissolves the oxide as it forms. This creates a surface covered in nanopores, which are tiny holes between 10 and 150 nanometers in diameter. These pores allow the current and electrolyte to reach the underlying metal so the layer can grow thicker.

There are several distinct types of anodizing based on the chemicals used. The oldest method is chromic acid anodizing, also known as Type I. This is often used in specific industrial applications. Type II anodizing uses sulfuric acid and is very common. Type III is known as sulfuric acid hard anodizing, which produces thicker and harder films. Other variations include oxalic acid anodizing, which was patented in Japan in 1923. Phosphoric acid processes are more recent developments used primarily as pretreatments for organic paints or adhesives.

Anodized titanium colors
Anodized titanium colors

The history of industrial anodizing began in 1923. It was first used on a large scale to protect Duralumin parts on seaplanes from corrosion. This early method was called the Bengough–Stuart process. It was documented in the British defence specification DEF STAN 03-24/3. In 1927, Gower and O'Brien patented the first sulfuric acid anodizing process. Sulfuric acid soon became the most common electrolyte used in the industry. While anodized aluminum extrusions were popular in architecture during the 1960s and 1970s, they have since been replaced by plastics and powder coating.

Anodizing has specific physical properties that must be managed. While it makes the surface harder, it does not increase the overall strength of the metal object. The resulting anodic film is an insulator, meaning it does not conduct electricity. The thickness of the coating can vary greatly, from under 0.5 micrometers for decorative work to 150 micrometers for architectural needs. Anodizing also changes the dimensions of a part. Because the oxide grows into and out of the surface equally, the part's dimensions increase by half the oxide thickness on each surface. If a part is anodized on all sides, the total linear dimensions increase by the full thickness of the oxide.

There are several notable facts regarding the durability of these coatings. Anodic films are generally stronger and more adherent than most paints or metal plating. However, they are also more brittle. This makes them less likely to peel from wear, but more likely to crack from thermal stress. If a coating is exposed to temperatures above 80 °C (353 K), it may crack. Interestingly, while the coating can crack, it will not peel off the metal. Additionally, the melting point of aluminum oxide is 2050 °C (2323 K), which is much higher than the 658 °C (931 K) melting point of pure aluminum.

Anodizing connects to many different fields, from consumer electronics to heavy industry. You can find anodized surfaces on smartphones, MP3 players, cameras, and flashlights. It is also used in cookware, sporting goods, and firearms. In the aerospace and military sectors, strict specifications like MIL-A-8625 define the required quality for different types of anodizing. The process is also vital for creating dielectric films used in electrolytic capacitors. By controlling the chemistry and electrical current, manufacturers can tailor the metal surface for almost any environment.

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