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Anatase

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Anatase is a specific mineral form of titanium dioxide, which is a chemical compound known as TiO2.

Anatase crystal structure
Anatase crystal structure

In the study of minerals, anatase is classified as a polymorph. This means it shares the same chemical formula as other minerals but has a different internal crystal structure. While pure titanium dioxide is colorless or white, natural anatase is usually a black solid. This color change occurs because of various impurities found within the mineral. It belongs to the tetragonal crystal system, meaning its internal arrangement follows a specific geometric pattern.

There are several other natural polymorphs of titanium dioxide. These include brookite, akaogiite, and rutile. Among these, rutile is the most common and most stable form. Anatase is considered metastable at all temperatures and pressures. This means it is not the most stable state for the material. However, anatase is often the first phase to form during many natural processes. This happens because it has a lower surface energy than rutile. Eventually, if temperatures rise, anatase will transform into the more stable rutile phase.

Scientists can distinguish anatase from rutile by looking at its physical shape and properties. Both minerals crystallize in the tetragonal system and share the same degree of symmetry. However, their interfacial angles are different. Anatase has a common octahedral crystal habit, which means it forms eight-sided shapes. It has an angle of 82°9' over its polar edge. In comparison, rutile octahedra have a much smaller angle of 56°52½'. This steeper angle gives anatase crystals a skinnier appearance and a longer vertical axis.

Anatase-Quartz-221342
Anatase-Quartz-221342

Other physical measurements also set these minerals apart. Anatase is less hard than rutile. On the Mohs scale of mineral hardness, anatase scores between 5.5 and 6, while rutile scores between 6 and 6.5. It is also less dense. The specific gravity of anatase is about 3.9, whereas rutile is about 4.2. Optically, the two minerals behave differently as well. Anatase is optically negative, but rutile is optically positive. Additionally, anatase shows a stronger adamantine or metallic-adamantine luster than rutile.

The history of naming this mineral involves several different scientists. The modern name was introduced by René Just Haüy in 1801. The term comes from the word for "stretching out." This refers to how the crystals appear stretched along an axis. An earlier name was octahedrite, which was given by Horace Bénédict de Saussure. He chose this name because of the acute octahedral shape of the crystals. Other obsolete names include oisanite, named by Jean-Claude Delamétherie, and dauphinite, named after the French locality of Le Bourg-d'Oisans.

Anatase appears in various environments and growth habits. One common type consists of simple acute octahedra. These are often indigo-blue to black with a steely luster. These crystals are abundant in the granite and mica schist of Le Bourg-d'Oisans, France.

Anatase-Quartz-221342
Anatase-Quartz-221342

Microscopic versions are also found in sedimentary rocks like sandstones, clays, and slates. A second type of growth habit features numerous pyramidal faces. These crystals are flatter or prismatic and appear honey-yellow to brown. These were once thought to be a form of the mineral xenotime called wiserine. They are found in the gneiss of the Alps, specifically near Binnenthal in Switzerland.

In modern science, anatase is highly valued for its potential as a semiconductor. Because of this, it is often prepared synthetically in laboratories. Scientists use chemical methods like the sol-gel process to create crystalline anatase. This can involve the controlled hydrolysis of titanium tetrachloride or titanium ethoxide. During synthesis, researchers often add dopants. These impurities help control the surface chemistry, electronic structure, and morphology of the sample. Anatase also has practical uses in everyday technology. For example, a thin film of TiO2 coated on glass can provide antifogging and self-cleaning properties when exposed to ultraviolet radiation.

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File:Anatase crystal structure.png
Anatase crystal structure.png
File:Anatase-Quartz-221342.jpg
Anatase-Quartz-221342.jpg
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