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Aluminium carbide

physical science Maturity 11-13 Next article →

Aluminium carbide is a unique chemical compound. It appears as crystals that are pale yellow or brown. This substance is a type of carbide made from aluminium. It is a very hard material. In fact, it has a hardness similar to topaz.

Because it is so hard, people use it as an abrasive. This means it can be used in high-speed cutting tools.

This material has a very unusual crystal structure. It is made of alternating layers of aluminium and carbon. Each aluminium atom connects to four carbon atoms. This forms a shape called a tetrahedral arrangement. The carbon atoms live in two different environments. One type forms a deformed octahedron of six aluminium atoms. The other forms a distorted trigonal bipyramidal structure.

Scientists make this compound in a few ways. One way is a direct reaction between aluminium and carbon. They do this inside an electric arc furnace. Another way starts with alumina. However, that way is less favorable because it makes carbon monoxide. It can also form when silicon carbide reacts with aluminium. This can make the material more brittle.

Aluminium carbide reacts strongly with water through a process called hydrolysis. This reaction produces methane gas and a lot of heat. One study looked at adding 10g of aluminium carbide to 10g of water. This reached a maximum temperature of 127 degrees Celsius in 11 minutes. Another study used 20g of aluminium carbide and 10g of water. That reaction reached a maximum temperature of 115 degrees Celsius.

Sometimes this substance forms when it is not wanted. It can be an impurity in technical calcium carbide. It also forms on graphite electrodes during the making of aluminium. In some metal mixtures, it can make the material weaker. This happens when it forms on silicon carbide particles. People can stop this by using a special coating. They might use an oxide, a nitride, or a layer of silica.

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