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Alum

physical science Maturity 7-9 Next article →

Alum is a specific type of chemical compound known as a hydrated double sulfate salt. It is defined by a general formula where a trivalent metal, such as aluminum, combines with a monovalent cation like potassium or ammonium.

Potassium alum octahedral like crystal
Potassium alum octahedral like crystal

While the term can refer to many different variations, it most commonly describes potassium alum, which has the formula KAl(SO4)2·12H2O. This substance is highly significant because of its unique chemical properties and its wide range of uses in industry, medicine, and art. Understanding alum requires looking at its complex molecular structure and how it interacts with other substances.

The mechanism of an alum crystal involves a specific arrangement of atoms and water molecules. In these compounds, each metal ion is surrounded by six water molecules. This makes them hydrated salts. When these crystals are heated, a process occurs where the water of crystallization is driven off. As the water leaves, the salt froths and swells. Eventually, it turns into an amorphous powder.

Kaaliumi maarjase monikristallid2
Kaaliumi maarjase monikristallid2

Chemically, alums are soluble in water and possess an acidic nature. This acidity is demonstrated when they turn blue litmus paper red. They also exhibit an astringent quality, which means they can cause the contraction of body tissues.

There are several distinct types of alums categorized by their chemical makeup. The most common are aluminum-based alums, which are named after the monovalent cation they contain. These include potassium alum, also called potash alum, sodium alum, and ammonium alum.

Chromium Alum - top view
Chromium Alum - top view

Beyond aluminum, other trivalent metals can form alums. A notable example is chrome alum, a dark violet crystal of potassium chromium sulfate. Some alums also replace sulfur with selenium, creating selenate-containing alums. These are known to be strong oxidizing agents. Furthermore, alums are classified by their crystal structures into three groups: α-alums, β-alums, and γ-alums.

The history of alum is recorded back to antiquity. The Greek historian Herodotus mentioned Egyptian alum as a valuable commodity. On the island of Lesbos, archaeological evidence shows that potassium alum was produced from a mineral called alunite as far back as the 2nd century CE. Roman writers like Pliny the Elder provided detailed descriptions of substances called alumen. Pliny noted they were used for dyeing and medicine. During the Middle Ages, alum was a vital export from the Chad region. It was transported to markets in Egypt, Morocco, and Europe to serve the textile industry.

Tawas (alum), a traditional deodorant in the Philippines 01
Tawas (alum), a traditional deodorant in the Philippines 01

Scientific understanding of alum evolved through many corrections and discoveries. In the early 1700s, G. E. Stahl incorrectly claimed alum was produced from limestone and sulfuric acid. This was later corrected by Johann Heinrich Pott and Andreas Sigismund Marggraf. Marggraf demonstrated that alumina, a precipitate from alum solutions, was actually an ingredient in common clay. In 1767, Torbern Bergman discovered that only potassium or ammonium could convert aluminum sulfate into alum. The exact composition was finally determined in 1797 by Louis Vauquelin. He proved that common alum is a double salt composed of sulfuric acid, alumina, and potash.

Alum has many surprising and practical applications. In the jewelry industry, a concentrated bath of hot alum is used to remove broken steel drill bits from precious metals. Because alum corrodes carbon steel but does not react significantly with gold, silver, or copper, it can dissolve the bit without damaging the jewelry.

Kristall med
Kristall med

In the Philippines, potassium alum is known as tawas and is used as a traditional, scentless deodorant. In the past, alum was also used in food production. In Britain, it was used to bleach flour. However, this became dangerous in the 19th century. Some bakers added excessive amounts of alum to make low-grade flour appear whiter. This caused toxic concentrations that could lead to chronic diarrhea or even death in children.

Today, alum remains essential to many broader industrial and scientific systems. In water treatment, it is used as a flocculant to clarify cloudy liquids through a process called flocculation. It also serves as a mordant, which is a substance used to set dyes on fabrics. In medicine, aluminum hydroxide gel is used as a vaccine adjuvant. Even in the world of physics, the study of alum has been important. In 1927, James M. Cork and Lawrence Bragg used the X-ray crystal structures of alums to help develop the technique of isomorphous replacement.

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🖼️ Images & Media (5)
File:Kaaliumi maarjase monikristallid2.JPG
Kaaliumi maarjase monikristallid2.JPG
File:Potassium alum octahedral like crystal.jpg
Potassium alum octahedral like crystal.jpg
File:Tawas (alum), a traditional deodorant in the Philippines 01.jpg
Tawas (alum), a traditional deodorant in...
File:Kristall med.jpg
Kristall med.jpg
File:Chromium Alum - top view.jpg
Chromium Alum - top view.jpg
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