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Alkene

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Alkenes are a special group of molecules called hydrocarbons. These molecules are made only of carbon and hydrogen atoms.

Ethylene-3D-vdW
Ethylene-3D-vdW

What makes an alkene unique is a carbon-carbon double bond. This double bond is a very strong connection between two atoms. It is stronger than a single bond, but it is not twice as strong. Because of this bond, alkenes are more reactive than other hydrocarbons. This means they change more easily during chemical reactions.

Ethylene 3D
Ethylene 3D

To understand how they work, we can look at the bond itself. A double bond is actually made of two different parts. The first part is called a sigma bond. The second part is called a pi bond. The pi bond is much weaker than the sigma bond. This bond sits outside the main axis of the molecule. It also makes it very hard for the atoms to rotate. Because they cannot rotate easily, the shapes of the molecules stay fixed. This leads to something called isomerism, where molecules have the same parts but different shapes.

Cis-trans example
Cis-trans example

Scientists use specific names to describe these different shapes. When groups are on the same side, it is called cis. This comes from the Latin words for "on this side of." If the groups are on opposite sides, it is called trans. For more complex molecules, scientists use E and Z notation. These come from German words meaning "opposite" and "together."

EZalkenes2
EZalkenes2

In the Z version, the most important groups are together. In the E version, they are on opposite sides. These small changes in position can change how the molecule acts.

There are many different types of alkenes depending on their size. The simplest one is called ethylene, or ethene. Ethylene is produced on a huge scale in industry.

AlkenylGroups
AlkenylGroups

Small alkenes like ethylene, propylene, and butene are gases at room temperature. As the molecules get bigger, they change into liquids. The very largest alkenes are waxy solids. Even their smells can change. Ethylene has a sweet and musty odor, but some other alkenes have very unpleasant smells.

Knowing how to name these molecules is a big job. The International Union of Pure and Applied Chemistry, or IUPAC, sets the rules. For a simple chain, scientists change the ending of the name to "-ene." For example, the alkane ethane becomes the alkene ethene. If the molecule has branches, the rules get more detailed. Scientists must find the longest chain of carbons first. They then number the carbons to show exactly where the double bond is located.

Alkene nomenclature
Alkene nomenclature

This helps everyone in science know exactly which molecule they are talking about.

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🖼️ Images & Media (24)
File:Ethylene-3D-vdW.png
Ethylene-3D-vdW.png
File:Ethylene 3D.png
Ethylene 3D.png
File:Alkene nomenclature.svg
Alkene nomenclature.svg
File:Cis-trans example.svg
Cis-trans example.svg
File:EZalkenes2.png
EZalkenes2.png
File:AlkenylGroups.png
AlkenylGroups.png
File:Ear.png
Ear.png
File:Biadamantylidene-bromonium-ion-from-xtal-1994-2D-skeletal.png
Biadamantylidene-bromonium-ion-from-xtal-1...
File:HBr-addition.svg
HBr-addition.svg
File:Diels-Alder (1,3-butadiene + ethylene) red.svg
Diels-Alder (1,3-butadiene + ethylene) red.svg
File:Schenck ene reaction.svg
Schenck ene reaction.svg
File:DCDmodel.png
DCDmodel.png

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