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Volatile (astrogeology)

physical science Maturity 9-11 Next article →

In the study of astrogeology, scientists focus on a specific group of substances called volatiles. Volatiles are chemical elements and compounds that can be easily vaporized. This means they can turn into gas quite readily. This is the opposite of refractory substances, which are materials that do not vaporize easily. By studying volatiles, planetary scientists can learn about the crusts and atmospheres of various planets and moons. Common volatiles include hydrogen, nitrogen, oxygen, and water. Other examples are ammonia, methane, carbon dioxide, and noble gases. They also include substances like sulfur dioxide, phosphine, and various halogens.

Planetary scientists use specific categories to group these materials based on their melting points. Volatiles with exceptionally low melting points, such as helium and hydrogen, are classified as gases. Volatiles with melting points above 100 K (–173 °C or –280 °F) are referred to as ices. It is important to note that these terms can describe substances in solid, liquid, or gas forms. For example, Jupiter and Saturn are known as gas giants. Uranus and Neptune are called ice giants. Even in these giant planets, the interior material is often a hot, highly dense fluid. In Neptune, temperatures may even reach 5,100 °C.

On Earth, the term volatiles is used frequently in igneous petrology. This branch of science studies how volatiles behave within magma, which is molten rock. Magma is usually composed of 95% to 99% liquid rock. Even though the percentage of gas is very small, it represents a massive volume when it expands. This expansion is what generates explosive volcanic eruptions. The type of eruption depends on the viscosity, or thickness, of the magma. Felsic magma has a high silica (SiO2) content and high viscosity. This type of magma often produces explosive eruptions. In contrast, mafic magma has a lower silica content and lower viscosity. These tend to result in effusive eruptions or lava fountains.

Several factors control how volatiles disperse within magma. These factors include the temperature, the composition of the magma, and the confining pressure. Pressure and composition are considered the most important parameters. Scientists must understand solubility to predict how magma behaves. Solubility is the ability of a liquid to hold a dissolved substance. For example, water in rhyolite magma follows a specific mathematical relationship involving pressure. As magma rises toward the surface, the confining pressure decreases. This decrease in pressure causes volatiles to come out of solution. This process is known as exsolving. When volatiles exsolve, they create bubbles that circulate and connect into a network.

Magma can exist in different states of saturation regarding its volatiles. If a magma holds less water than the maximum amount possible, it is undersaturated. Most magma in the deep crust and mantle is undersaturated. When magma reaches the maximum amount of water it can hold, it is considered saturated. If the magma continues to rise and more water is dissolved, it becomes supersaturated. In a supersaturated state, the extra volatiles are ejected as bubbles or water vapor. Carbon dioxide behaves differently than water because it has much lower solubility. Because of this, carbon dioxide tends to exsolve at greater depths than water. This can cause carbon dioxide bubbles to leak through cracks in a caldera.

The formation of these bubbles begins with a process called nucleation. Nucleation occurs when a volatile becomes saturated. Molecules can group together spontaneously through a process called homogeneous nucleation. However, nucleation can also happen more easily if there are solid crystals present in the magma. These crystals act as perfect potential nucleation sites for the bubbles. If nucleation is delayed, the magma may become significantly supersaturated. This can cause bubbles to form much later and more suddenly. If magma rises rapidly to the surface, the system stays out of equilibrium. This rapid rise affects how the distance between bubbles is determined.

Understanding volatiles helps us connect many different scientific fields. It links the study of planetary atmospheres to the study of deep volcanic systems. By measuring the amount of hydrogen chloride, hydrogen fluoride, or sulfur dioxide released, scientists can learn about the magma's composition. The study of volatiles also touches on cometary activity. In the region inside Jupiter's orbit, the sublimation of water ice drives comets. Even far out in space, supervolatiles like carbon monoxide and carbon dioxide can generate cometary activity. This makes volatiles a central topic for understanding the history and behavior of our solar system.

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