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Noble gas

physical science Maturity 11-13 Next article →

The noble gases are a unique group of chemical elements found in Group 18 of the periodic table.

Electron shell 010 Neon - no label
Electron shell 010 Neon - no label

This group includes helium, neon, argon, krypton, xenon, radon, and the synthetic element oganesson. Historically, these elements were called inert gases because they show very little chemical reactivity. This means they do not easily combine with other substances to form compounds. Under standard conditions, the first six members are colorless, odorless, and monatomic gases. Being monatomic means they exist as single, individual atoms rather than molecules. They are also known for having cryogenic boiling points, which are extremely low temperatures.

Noble gas extraction and purification apparatus
Noble gas extraction and purification apparatus

The chemical stability of noble gases is explained by their specific electron configuration. Every atom has electrons arranged in shells around a nucleus. For most noble gases, the outermost shell, or valence shell, is completely full.

Electron shell 010 Neon - no label
Electron shell 010 Neon - no label

In 1916, physicist Gilbert N. Lewis formulated the octet rule to describe this. The rule states that having eight electrons in the outer shell is the most stable arrangement. Because their shells are already full, these atoms have little tendency to gain or lose electrons. This lack of need for more electrons makes them highly unreactive. While scientists once thought they could not react at all, a few hundred noble gas compounds have since been discovered.

Xenon-tetrafluoride-3D-vdW
Xenon-tetrafluoride-3D-vdW

There are several distinct types of noble gases within this group. The first is helium, which is the lightest element and has a unique boiling point lower than any other known substance. Next are the gases like neon and argon, which are commonly used in industry. Moving down the group, the atoms get larger and heavier, such as krypton and xenon. Radon is a heavier, radioactive element that is not stable. Finally, there is oganesson, which is a synthetic element. Unlike the others, oganesson is predicted to be a solid under standard conditions due to relativistic effects.

First Ionization Energy blocks
First Ionization Energy blocks

The history of these gases is a story of scientific discovery spanning over a century. In 1868, Pierre Janssen and Joseph Norman Lockyer discovered helium by observing the Sun's chromosphere. They named it after the Greek word for the Sun, "helios." Later, in 1895, Lord Rayleigh noticed that nitrogen from the air had a different density than nitrogen from chemical reactions. He and William Ramsay worked together to isolate argon, which they named after the Greek word for "idle." Ramsay later used fractional distillation to find krypton, neon, and xenon in 1898. These discoveries were so significant that Rayleigh and Ramsay shared Nobel Prizes in 1904.

Helium spectrum
Helium spectrum

Noble gases are vital to many modern technologies and industries. Argon makes up about 0.94% of the Earth's atmosphere by volume. Because it is unreactive, it is used as a shielding gas in welding and as a filler in incandescent light bulbs. Helium provides buoyancy for blimps and balloons, as seen in large airships.

Goodyear-blimp
Goodyear-blimp

Because of their low boiling points, helium and neon are also excellent refrigerants. Xenon is used in high-intensity applications, such as xenon short-arc lamps.

Xenon short arc 1
Xenon short arc 1

Even radon has a role, though it is usually isolated from the decay of radium, thorium, or uranium.

Scientists obtain these gases through different methods depending on the element. Most noble gases, except for radon, are extracted from the air. This is done using a process called fractional distillation, where air is liquefied and then separated. Helium can also be found as a byproduct of mining natural gas. Radon is different because it is a product of radioactive decay. In contrast, oganesson is entirely man-made. It was created in 2006 by scientists at the Joint Institute for Nuclear Research and Lawrence Livermore National Laboratory. They produced it by bombarding californium with calcium.

Noble gas extraction and purification apparatus
Noble gas extraction and purification apparatus

The study of noble gases has deeply influenced our understanding of atomic physics. Early failed attempts to react argon with fluorine helped scientists build better theories. These efforts eventually led Niels Bohr to propose his model of electron shells in 1913. The weak forces between noble gas atoms, known as London dispersion forces, also helped scientists study intermolecular interactions. In 1924, John Lennard-Jones used argon data to help model these forces. Today, the noble gases continue to be essential for studying everything from quantum mechanics to the structure of the universe.

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🖼️ Images & Media (11)
File:Helium spectrum.jpg
Helium spectrum.jpg
File:First Ionization Energy blocks.svg
First Ionization Energy blocks.svg
File:Electron shell 010 Neon - no label.svg
Electron shell 010 Neon - no label.svg
File:Xenon-tetrafluoride-3D-vdW.png
Xenon-tetrafluoride-3D-vdW.png
File:Endohedral fullerene.png
Endohedral fullerene.png
File:XeF2.svg
XeF2.svg
File:Modern 3T MRI.JPG
Modern 3T MRI.JPG
File:Goodyear-blimp.jpg
Goodyear-blimp.jpg
File:Xenon short arc 1.jpg
Xenon short arc 1.jpg
File:Giggenbach_Bottle.jpg
Giggenbach_Bottle.jpg
File:Noble gas extraction and purification apparatus.png
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