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Thallium

physical science Maturity 11-13 Next article →

Thallium is a unique chemical element with the symbol Tl and atomic number 81. It is a silvery-white post-transition metal that is quite soft. In fact, it is malleable and sectile enough to be cut with a knife at room temperature.

Thallium rod corroded
Thallium rod corroded

While it has a metallic luster, it does not stay shiny for long. When exposed to air, it quickly tarnishes to a bluish-gray tinge. This makes it look similar to the metal lead. A heavy layer of oxide builds up on the surface if it is left in the air. To prevent this, the metal can be preserved by immersion in oil.

The chemistry of thallium is driven by its electrons. A single thallium atom contains 81 electrons. These are arranged in a specific electron configuration: [Xe]4f14 5d10 6s2 6p1. The three outermost electrons in the sixth shell are known as valence electrons. Because of a phenomenon called the inert pair effect, the 6s electron pair is relativistically stabilised. This makes it harder for those electrons to join in chemical bonding. As a result, very few electrons are available for metallic bonding. This makes thallium behave similarly to its neighbors, mercury and lead. It is a highly electrically conducting metal with a low melting point of 304 °C.

Thallium typically forms two different oxidation states, which are +1 and +3. The +3 state behaves like other elements in group 13, such as aluminum or gallium. However, the +1 state is much more prominent in thallium. This state actually resembles the chemistry of alkali metals. In nature, thallium(I) ions are mostly found in potassium-based ores. Because they are so similar, living cells often handle thallium(I) ions like potassium ions (K+) through ion pumps. This similarity is one reason why the metal can be so dangerous to biological systems.

Two scientists discovered thallium independently in 1861. Their names were William Crookes and Claude-Auguste Lamy. They both used a newly developed method called flame spectroscopy. This technique allows scientists to see specific colors, or spectral lines, produced by elements in a flame. Thallium produces a very notable green spectral line. Because of this, Crookes named the element after the Greek word for "green shoot" or "twig."

Lamy isolated the metal through electrolysis in 1862. Crookes isolated it through precipitation and melting. Both men were awarded medals for their work at the International Exhibition in 1862, though a controversy over priority continued for some time.

Thallium is not found free in nature. Its concentration in the Earth's crust is estimated to be 0.7 mg/kg. It is mostly found in association with potassium-based minerals in granites, soils, and clays.

For commercial use, thallium is produced as a byproduct during the refining of heavy-metal-sulfide ores. This includes ores containing copper, lead, and zinc. The electronics industry uses approximately 65% of all thallium production. The remaining portion is used in glass manufacturing and the pharmaceutical industry.

Some versions of thallium are very useful in modern medicine. The radioisotope thallium-201 is used as an agent in nuclear medicine scans. Specifically, it is used during a type of nuclear cardiac stress test. This isotope is made by the neutron activation of stable thallium in a nuclear reactor. It is useful because it decays by electron capture, emitting X-rays and gamma rays. These emissions provide good imaging characteristics for doctors without providing an excessive radiation dose to the patient.

Despite these uses, thallium is highly toxic. Soluble thallium salts are nearly tasteless, which made them historically popular as rat poisons and insecticides. Because they are nonselectively toxic, many countries have banned or restricted them. In the United States, the use of thallium as a poison was banned by Presidential Executive Order 11643 in February 1972. Thallium has gained a dark reputation as "the poisoner's poison" or "inheritance powder." One common sign of thallium poisoning in humans is hair loss.

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