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Polyethylene

physical science Maturity 7-9 Next article →

Polyethylene is the most common plastic used around the world today.

Polyethylene
Polyethylene

It is a polymer, which is a large molecule made of many smaller parts. These small building blocks are called ethylene.

CNX Chem 20 01 monomer
CNX Chem 20 01 monomer

Scientists use polyethylene to make many things like plastic bags, bottles, and jars. It accounts for 34% of the total plastics market. Over 100 million tonnes of these resins are produced every single year. Because it is strong and resists chemicals, it is a very popular choice for packaging.

Polyethylene-repeat-2D
Polyethylene-repeat-2D

Making polyethylene is a way of joining many ethylene molecules together. This way it works is called polymerization.

PE-LD mechanism en
PE-LD mechanism en

To start, you need ethylene, which is a gas. When ethylene touches a catalyst, it begins to link up. A catalyst is a substance that helps a reaction happen. This process can happen at very high pressures. Sometimes, scientists use special tools to control how the chains grow. Some types have many branches, while others are very straight. These shapes change how the plastic feels and works.

People discovered polyethylene by accident more than once. In 1898, a German chemist named Hans von Pechmann made it while studying other things. Later, in 1933, Eric Fawcett and Reginald Gibson found it again in England. They used very high pressure to mix ethylene with benzaldehyde. It was hard to repeat the experiment at first because of tiny bits of oxygen. In 1935, a chemist named Michael Perrin found a way to make it work every time. This helped factories start making low-density polyethylene in 1939.

First polythene pillbox
First polythene pillbox

There are many different kinds of polyethylene with different uses. High-density polyethylene, or HDPE, is very strong and has straight molecules.

PE-HD schematic
PE-HD schematic

You can find HDPE in milk jugs, detergent bottles, and even water pipes.

Site Photo of HDPE Pipe
Site Photo of HDPE Pipe

Low-density polyethylene, or LDPE, is softer and more clear.

PE-LD schematic
PE-LD schematic

There is also a very tough version called ultra-high-molecular-weight polyethylene. This version is used for artificial hips and even bulletproof vests.

Stainless steel and ultra high molecular weight polythene hip replacement (9672239334)
Stainless steel and ultra high molecular weight polythene hip replacement (9672239334)

It is used because it is very hard to wear down.

Polyethylene is useful because it does not soak up water. It also protects things from strong acids or bases. However, these same strengths can cause problems for the Earth. Because it is so resilient, it does not break down easily in nature. If it is not thrown away the right way, it can stay in the environment for a long time. This makes it a type of pollutant that lasts a long time. We must be careful with how we use and dispose of it.

Say no to polythene. Sign. Nako, H.P. India
Say no to polythene. Sign. Nako, H.P. India
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🖼️ Images & Media (12)
File:Polyethylene-repeat-2D.png
Polyethylene-repeat-2D.png
File:First polythene pillbox.JPG
First polythene pillbox.JPG
File:CNX Chem 20 01 monomer.png
CNX Chem 20 01 monomer.png
File:Stainless steel and ultra high molecular weight polythene hip replacement (9672239334).jpg
Stainless steel and ultra high molecular...
File:Site Photo of HDPE Pipe.jpg
Site Photo of HDPE Pipe.jpg
File:PE-HD schematic.svg
PE-HD schematic.svg
File:PE-LLD schematic.svg
PE-LLD schematic.svg
File:PE-LD schematic.svg
PE-LD schematic.svg
File:PE-LD mechanism en.svg
PE-LD mechanism en.svg
File:Crosslinking PE scheme en.svg
Crosslinking PE scheme en.svg
File:Polyethylene.jpg
Polyethylene.jpg
File:Say no to polythene. Sign. Nako, H.P. India.jpg
Say no to polythene. Sign. Nako, H.P. India.jpg
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