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Partial pressure

physical science Maturity 9-11 Next article →

Air is not just one thing. It is a mixture of many different gases. These gases include nitrogen, oxygen, argon, and carbon dioxide. Each gas in a mixture has its own individual push. We call this push the partial pressure.

Dalton's law of partial pressures
Dalton's law of partial pressures

You can imagine one gas sitting in a room all by itself. Its partial pressure is the pressure it would have if it were alone. When you mix different gases together, they all push at once. The total pressure of the whole mixture is the sum of every gas's partial pressure.

Schematic Depicting Dalton's Law-en
Schematic Depicting Dalton's Law-en

This way of working is called Dalton's Law. It works well because gas molecules are often very far apart. In an ideal gas, these molecules do not really interact with each other. This means they can each act as if they are alone. You can also look at the volume of these gases. A gas in a mixture has a partial volume. This is the space it would take up at the total pressure.

Dalton's law of partial pressures
Dalton's law of partial pressures

This helps scientists understand how much of one gas is in a large mix.

Partial pressure also explains how gases move into liquids. This is very important for your body to work. For example, oxygen moves from your lungs into your blood. This movement is driven by differences in partial pressure. In medicine, doctors call this blood gas tension.

Dalton's law of partial pressures
Dalton's law of partial pressures

Gases also follow Henry's law when they dissolve. This law says the amount of gas in a liquid depends on its partial pressure above the liquid. If the push of the gas is higher, more of it will dissolve.

Divers must be very careful with partial pressure underwater. When a diver goes deep, the total pressure increases quickly. This makes the partial pressure of every gas in their tank go up too. If the oxygen partial pressure drops below 0.16 bar absolute, a person might pass out. This is called hypoxia. However, if the oxygen push is too high, it can become toxic. The NOAA Diving Manual says divers should stay below 1.6 bar absolute for oxygen.

vapor pressure chart
vapor pressure chart

They also watch out for narcosis from other gases.

Liquids also have a special kind of push called vapor pressure. This is a measure of how much a liquid wants to turn into a gas. A liquid with a high vapor pressure will evaporate very easily. This pressure also affects when a liquid boils. A liquid boils when its vapor pressure matches the surrounding atmospheric pressure. For example, methyl chloride has a very high vapor pressure. It also has a very low boiling point of −24.2 °C.

vapor pressure chart
vapor pressure chart

At high places like Mount Everest, the lower pressure changes how things boil.

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🖼️ Images & Media (3)
File:Dalton's law of partial pressures.svg
Dalton's law of partial pressures.svg
File:Schematic Depicting Dalton's Law-en.svg
Schematic Depicting Dalton's Law-en.svg
File:vapor_pressure_chart.svg
vapor_pressure_chart.svg
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