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OLED

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An organic light-emitting diode, or OLED, is a specialized type of light-emitting diode (LED). Unlike standard LEDs, which use crystalline solid structures, OLEDs use an emissive layer made of organic compound films.

OLED schematic
OLED schematic

These organic materials emit light when they respond to an electric current. Because they use organic layers, these devices can be made very thin, flexible, or even transparent.

OLED transparent
OLED transparent

This unique property makes them essential for modern digital displays. You can find them in television screens, computer monitors, and portable devices like smartphones and handheld game consoles. They are also being researched for use in solid-state lighting.

The mechanism of an OLED relies on the movement of charges through organic semiconductors. These materials have conductivity levels ranging from insulators to conductors.

OLED schematic
OLED schematic

An OLED is built with an organic layer situated between two electrodes: the anode and the cathode. Typically, at least one electrode is transparent. To make light, a voltage is applied so the anode is positive compared to the cathode. Electrons flow from the cathode into the lowest unoccupied molecular orbital (LUMO) of the organic layer. Simultaneously, "holes" are injected from the anode into the highest occupied molecular orbital (HOMO).

OLED schematic
OLED schematic

Electrostatic forces pull these electrons and holes toward each other. When they meet, they recombine to form an exciton, which is a bound state of the electron and hole. As the exciton decays, the electron relaxes to a lower energy level and releases energy as visible light. The specific frequency, or color, of this light depends on the band gap, which is the energy difference between the HOMO and LUMO.

OLED technology can be organized into different families and control schemes. There are two main families: those based on small molecules and those using polymers.

Polyphenylene vinylene
Polyphenylene vinylene

Additionally, adding mobile ions to an OLED creates a light-emitting electrochemical cell (LEC), which operates slightly differently. To manage the pixels on a screen, manufacturers use two primary control schemes. A passive-matrix (PMOLED) scheme controls each row and line sequentially, one by one. In contrast, an active-matrix (AMOLED) scheme uses a thin-film transistor (TFT) backplane. This allows the device to directly access and switch each individual pixel on or off. AMOLED is preferred for higher resolution and larger display sizes.

The history of OLED is a long journey of scientific discovery. In the early 1950s, André Bernanose and his colleagues at Nancy-Université first observed electroluminescence in organic materials. They applied high alternating voltages to materials like acridine orange dye. In 1960, Martin Pope at New York University developed electrode contacts that are the basis for modern charge injection. By 1963, Pope's group observed direct current electroluminescence using a silver electrode at 400 volts. In 1965, Wolfgang Helfrich and W. G. Schneider produced the first double injection recombination electroluminescence. Later, in 1974, Roger Partridge created the first Polymer LED (PLED). His work used a film of polyvinylcarbazole up to 2.2 micrometers thick.

Practical, efficient OLEDs arrived through major breakthroughs in the late 20th century. In 1987, chemists Ching Wan Tang and Steven Van Slyke at Eastman Kodak built the first practical OLED device. They used a two-layer structure with separate hole and electron transporting layers. This design allowed recombination to happen in the middle of the organic layer, which improved efficiency and lowered operating voltage. In 1990, J. H. Burroughes reported a high-efficiency green light-emitting polymer device using 100nm thick films. By 1995, J. Kido and his team pioneered white OLEDs, which led to commercialized OLED-backlit displays and lighting.

Aquis Plaza OLED Kunstwerk
Aquis Plaza OLED Kunstwerk

Commercialization progressed rapidly through the late 1990s and early 2000s. In 1999, Kodak and Sanyo announced the world's first 2.4-inch active-matrix, full-color OLED display. By 2002, they presented a 15-inch HDTV prototype based on white OLEDs. Manufacturing of small molecule OLEDs began in 1997 with Pioneer Corporation, followed by TDK in 2001. Samsung Display became one of the largest manufacturers after its predecessor, Samsung-NEC, grew in 2002.

Dynamic AMOLED
Dynamic AMOLED

A major milestone for home entertainment occurred in 2007, when Sony released the XEL-1, the first OLED television.

More recently, in 2017, JOLED began the first commercial shipment of inkjet-printed OLED panels.

OLED technology connects to many different fields of science and engineering. In materials science, researchers study how to use doping to increase radiative efficiency or change the wavelength of light emission. They also work on graded heterojunction architectures to improve quantum efficiency. For example, a 2011 development improved quantum efficiency up to 19% by varying material composition within the emissive layer. This technology also links to the field of plastic electronics. Because OLEDs can be made flexible, they are vital for the development of foldable smartphones.

Structures of BEOLED vs. TEOLED
Structures of BEOLED vs. TEOLED

They also enable advanced features like transparent displays used with optical fingerprint scanners.

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🖼️ Images & Media (14)
File:OLED transparent.jpg
OLED transparent.jpg
File:OLED schematic.svg
OLED schematic.svg
File:AlumQ3.svg
AlumQ3.svg
File:Polyphenylene vinylene.svg
Polyphenylene vinylene.svg
File:Ir(mppy)3.svg
Ir(mppy)3.svg
File:Structures of BEOLED vs. TEOLED.png
Structures of BEOLED vs. TEOLED.png
File:Sony's Super Top Emission OLED.png
Sony's Super Top Emission OLED.png
File:Light Emitting Polymer display partially failed.jpg
Light Emitting Polymer display partially...
File:Oled display alterung.jpg
Oled display alterung.jpg
File:Nexus one screen microscope.jpg
Nexus one screen microscope.jpg
File:OLEDScreen.jpg
OLEDScreen.jpg
File:Aquis Plaza OLED Kunstwerk.jpg
Aquis Plaza OLED Kunstwerk.jpg

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